Radical deoxygenaton of secondary and primary alcohols with phenylsilane

Derek H.R. Barton, Doo Ok Jang, Joseph C. Jaszberenyi

Research output: Contribution to journalArticle

48 Citations (Scopus)

Abstract

Thionocarbonates and xanthates formed from secondary and primary alcohols are easily deoxygenated in 85-100% yield by radical deoxygenation with phenylsilane and 2,2′ -azobisisobutyronitrile or benzoyl peroxide in boiling toluene.

Original languageEnglish
Pages (from-to)435-438
Number of pages4
JournalSynlett
Volume1991
Issue number6
DOIs
Publication statusPublished - 1991 Jun

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Benzoyl Peroxide
Toluene
Boiling liquids
Alcohols
azobis(isobutyronitrile)

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

Barton, Derek H.R. ; Jang, Doo Ok ; Jaszberenyi, Joseph C. / Radical deoxygenaton of secondary and primary alcohols with phenylsilane. In: Synlett. 1991 ; Vol. 1991, No. 6. pp. 435-438.
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Radical deoxygenaton of secondary and primary alcohols with phenylsilane. / Barton, Derek H.R.; Jang, Doo Ok; Jaszberenyi, Joseph C.

In: Synlett, Vol. 1991, No. 6, 06.1991, p. 435-438.

Research output: Contribution to journalArticle

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