Radical mono- and dideoxygenations with the triethylsilane + benzoyl peroxide system.

Derek H.R. Barton, Doo Ok Jang, Joseph Cs Jaszberenyi

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

Thionocarbonates and xanthates of primary and secondary alcohols, as well as dixanthates of vic-diols can easily be deoxygenated to the corresponding hydrocarbons or olefins with triethylsilane and benzoyl peroxide in high-yielding radical reactions.

Original languageEnglish
Pages (from-to)7187-7190
Number of pages4
JournalTetrahedron Letters
Volume32
Issue number49
DOIs
Publication statusPublished - 1991 Dec 2

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Benzoyl Peroxide
Alkenes
Hydrocarbons
Alcohols
triethylsilane

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Barton, Derek H.R. ; Jang, Doo Ok ; Jaszberenyi, Joseph Cs. / Radical mono- and dideoxygenations with the triethylsilane + benzoyl peroxide system. In: Tetrahedron Letters. 1991 ; Vol. 32, No. 49. pp. 7187-7190.
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Radical mono- and dideoxygenations with the triethylsilane + benzoyl peroxide system. / Barton, Derek H.R.; Jang, Doo Ok; Jaszberenyi, Joseph Cs.

In: Tetrahedron Letters, Vol. 32, No. 49, 02.12.1991, p. 7187-7190.

Research output: Contribution to journalArticle

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