Radical mono- and dideoxygenations with the triethylsilane + benzoyl peroxide system.

Derek H.R. Barton, Doo Ok Jang, Joseph Cs Jaszberenyi

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

Thionocarbonates and xanthates of primary and secondary alcohols, as well as dixanthates of vic-diols can easily be deoxygenated to the corresponding hydrocarbons or olefins with triethylsilane and benzoyl peroxide in high-yielding radical reactions.

Original languageEnglish
Pages (from-to)7187-7190
Number of pages4
JournalTetrahedron Letters
Volume32
Issue number49
DOIs
Publication statusPublished - 1991 Dec 2

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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