Rapid Formation of a Disordered Layer on Monoclinic BiVO4: Co-Catalyst-Free Photoelectrochemical Solar Water Splitting

Jung Kyu Kim, Yoonjun Cho, Myung Jin Jeong, Ben Levy-Wendt, Dongguen Shin, Yeonjin Yi, Dong Hwan Wang, Xiaolin Zheng, Jong Hyeok Park

Research output: Contribution to journalArticlepeer-review

24 Citations (Scopus)


A surface disordered layer is a plausible approach to improve the photoelectrochemical performance of TiO2. However, the formation of a crystalline disordered layer in BiVO4 and its effectiveness towards photoelectrochemical water splitting has remained a big challenge. Here, we report a rapid solution process (within 5 s) that is able to form a disordered layer of a few nanometers thick on the surface of BiVO4 nanoparticles using a specific solution with a controllable reducing power. The disordered layer on BiVO4 alleviates charge recombination at the electrode–electrolyte interface and reduces the onset potential greatly, which in turn results in a photocurrent density of approximately 2.3 mA cm−2 at 1.23 V versus the reversible hydrogen electrode (RHE). This value is 2.1 times higher than that of bare BiVO4. The enhanced photoactivity is attributed to the increased charge separation and transfer efficiencies, which resolve the intrinsic drawbacks of bare BiVO4 such as the short hole diffusion length of around 100 nm and poor surface oxygen evolution reactivity.

Original languageEnglish
Pages (from-to)933-940
Number of pages8
Issue number5
Publication statusPublished - 2018 Mar 9

Bibliographical note

Funding Information:
This research was supported by C1 Gas Refinery Program through the National Research Foundation of Korea(NRF) funded by the Ministry of Science, ICT & Future Planning (2016M3D3A1A01913254). This work was also supported by the NRF of Korea Grant funded by the Ministry of Science, ICT & Future Planning (2015M1A2A2074663, 2017R1A1A1A05000772 ) and the National Science Foundation Graduate Research Fellowship Program (DGE-114747). J.K.K. and Y.C. contributed to this work equally.

Publisher Copyright:
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

All Science Journal Classification (ASJC) codes

  • Environmental Chemistry
  • Chemical Engineering(all)
  • Materials Science(all)
  • Energy(all)


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