Rapid structural reorganization in thin films of block copolymer self-assembly

Jinsam Gong, Hyungju Ahn, Eunhye Kim, Hoyeon Lee, Sungmin Park, Moongyu Lee, Sumi Lee, Taewoo Kim, Eun Ae Kwak, Du Yeol Ryu

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13 Citations (Scopus)


In the present study, the thin films of a symmetric polystyrene-b- poly(methyl methacrylate) (PS-b-PMMA) were prepared on a neutral substrate and subjected to solvent annealing, sequentially coupled with thermal annealing for a short time. For this process, a P(S-r-MMA)-grafted substrate was used for surface neutrality to the PS and PMMA blocks. During solvent annealing with PMMA-selective acetone vapor, the block copolymer (BCP) films show a predominantly parallel orientation of the cylindrical PS microdomains over the underlying perpendicular PS cylinders on the substrate. Sequential thermal annealing of the BCP films for a short time led to efficient structural reorganization to an equilibrium morphology with the perpendicular orientation of the lamellar microdomains. This approach suggests a simple and useful route for directing the orientation of microdomain arrays in the thin films of BCP self-assembly.

Original languageEnglish
Pages (from-to)3570-3575
Number of pages6
JournalSoft Matter
Issue number13
Publication statusPublished - 2012 Apr 7

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Condensed Matter Physics

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    Gong, J., Ahn, H., Kim, E., Lee, H., Park, S., Lee, M., Lee, S., Kim, T., Kwak, E. A., & Ryu, D. Y. (2012). Rapid structural reorganization in thin films of block copolymer self-assembly. Soft Matter, 8(13), 3570-3575. https://doi.org/10.1039/c2sm07262a