Ratiometric and simultaneous estimation of Fe3+ and Cu 2+ ions: 1,3,5-substituted triethylbenzene derivatives coupled with benzimidazole

Doo Youn Lee, Narinder Singh, Doo Ok Jang

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Abstract

We synthesized a novel 1,3,5-substituted triethylbenzene derivative with a benzimidazole moiety as a binding and signalling subunit. The triethylbenzene platform was judiciously incorporated into the receptor design such that all the fluorophores are in close proximity to each other in order to facilitate stacking. The advantage of this approach lies in the fact that the receptor will offer a dual channel emission for the multiple ratiometric determination of metal ions. The sensor was tested in a CH3CN/H2O (7:3, v/v, pH 7.1) HEPES buffered solution and successfully developed for the ratiometric and simultaneous estimation of Fe3+ and Cu2+ ions in aqueous samples.

Original languageEnglish
Pages (from-to)3886-3890
Number of pages5
JournalTetrahedron Letters
Volume52
Issue number30
DOIs
Publication statusPublished - 2011 Jul 27

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All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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