Ratiometric determination of Hg2+ ions based on simple molecular motifs of pyrene and dioxaoctanediamide

Soo Kim Jun, Gil Choi Myung, Cheol Song Ki, Tai No Kyoung, Sangdoo Ahn, Suk Kyu Chang

Research output: Contribution to journalArticle

121 Citations (Scopus)

Abstract

(Chemical Equation Presented) A new podand-type dioxaoctanediamide-based chemosensor having two pyrene moieties was prepared, and its fluoroionophoric behaviors toward transition-metal ions were investigated. Pyrene-appended dioxaoctanediamide 1 showed a selective fluorescence quenching toward Hg 2+ ions over other transition-metal ions in an aqueous methanol solution. Unique responses in pyrene monomer and excimer emissions allowed selective ratiometric determination of Hg2+ ions in aqueous environments, and the detection limit was found to be 1.6 × 10 -6 M.

Original languageEnglish
Pages (from-to)1129-1132
Number of pages4
JournalOrganic Letters
Volume9
Issue number6
DOIs
Publication statusPublished - 2007 Mar 15

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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