Sila-heterocycles, ditrisyldibromodisiladioxetane (trisyl = C(SiMe3)3) 2 and ditrisyldibromodithiadisiletane 3, were generated at a low temperature from the reaction of trisylbromosilylenoid 1 with heterocumulenes such as phenyl isocyanate and phenyl isothiocyanate. The 29Si-NMRs of sila-heterocycles were then investigated. The reaction of cyclic compounds 2 and 3 with MeOH gave dimethoxy(trisyl)silanol 4 and dimethoxy(trisyl)silanethiol 5, respectively, through ring cleavage and substitution reactions. This work is the first investigation of the reactivity of silylenoid with heterocumulenes.
Bibliographical noteFunding Information:
This work was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science, and Technology ( 2010-0024877 ).
© 2015 Published by Elsevier B.V.
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry