Recovery properties after H2S catalytic poisoning of catalytic-type gas sensor with photo-catalysts and UV radiation have been examined. Each sensing material of the sensor consists of Pd, Pt supported on γ-Al2O3 and Pd/titanate, Pt/titanate nanotubes or TiO2 particles. Pd/titanate and Pt/titanate nanotubes photo-catalyst were synthesized by hydrothermal synthesis method. All the sensors were deactivated after 500 ppm H2S exposure for 20 h. The sensors with Pd/titanate or Pt/titanate nanotubes showed regenerated voltage response under UV radiation. However the sensor with TiO2 particles showed negligible regenerated voltage response. Regenerated voltage response with Pd/titanate or Pt/titanate nanotubes may stem from location of Pd or Pt catalyst on the titanate nanotube photo-catalyst.
Bibliographical noteFunding Information:
This research was performed for the Hydrogen Energy R&D Center, one of the 21st Century Frontier R&D Program, funded by the Ministry of Science and Technology of Korea.
All Science Journal Classification (ASJC) codes
- Materials Science(all)
- Physics and Astronomy(all)