Redox-active organometallic Ir complexes containing biphenyl-2,2′- diyl

Zheng Lu, Chul Ho Jun, Susan R. De Gala, Michel Sigalas, Odile Eisenstein, Robert H. Crabtree

Research output: Contribution to journalArticle

44 Citations (Scopus)

Abstract

The redox-active complexes [Ir(PPh3)2(biph)Cl] 3 and [Ir(PMe3)3(biph)Cl] 6 contain biphenyl-2,2-diyl (biph), the organometallic analogue of bipy; 3 shows an unexpected five-coordinate structure lying between T and Y geometry and oxidation of 6 by NOBF4 gives [Ir(PMe3)3(biphBF)Cl]+ (8)+, an unprecedented IrIV boryl complex.

Original languageEnglish
Pages (from-to)1877-1880
Number of pages4
JournalJournal of the Chemical Society, Chemical Communications
Issue number24
DOIs
Publication statusPublished - 1993 Dec 1

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Organometallics
Oxidation-Reduction
Oxidation
Geometry
diphenyl

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

Cite this

Lu, Zheng ; Jun, Chul Ho ; De Gala, Susan R. ; Sigalas, Michel ; Eisenstein, Odile ; Crabtree, Robert H. / Redox-active organometallic Ir complexes containing biphenyl-2,2′- diyl. In: Journal of the Chemical Society, Chemical Communications. 1993 ; No. 24. pp. 1877-1880.
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Redox-active organometallic Ir complexes containing biphenyl-2,2′- diyl. / Lu, Zheng; Jun, Chul Ho; De Gala, Susan R.; Sigalas, Michel; Eisenstein, Odile; Crabtree, Robert H.

In: Journal of the Chemical Society, Chemical Communications, No. 24, 01.12.1993, p. 1877-1880.

Research output: Contribution to journalArticle

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AU - Jun, Chul Ho

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AU - Eisenstein, Odile

AU - Crabtree, Robert H.

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