Abstract
The redox-active complexes [Ir(PPh3)2(biph)Cl] 3 and [Ir(PMe3)3(biph)Cl] 6 contain biphenyl-2,2-diyl (biph), the organometallic analogue of bipy; 3 shows an unexpected five-coordinate structure lying between T and Y geometry and oxidation of 6 by NOBF4 gives [Ir(PMe3)3(biphBF)Cl]+ (8)+, an unprecedented IrIV boryl complex.
| Original language | English |
|---|---|
| Pages (from-to) | 1877-1880 |
| Number of pages | 4 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 24 |
| DOIs | |
| Publication status | Published - 1993 Dec 1 |
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All Science Journal Classification (ASJC) codes
- Molecular Medicine
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Redox-active organometallic Ir complexes containing biphenyl-2,2′- diyl. / Lu, Zheng; Jun, Chul Ho; De Gala, Susan R.; Sigalas, Michel; Eisenstein, Odile; Crabtree, Robert H.
In: Journal of the Chemical Society, Chemical Communications, No. 24, 01.12.1993, p. 1877-1880.Research output: Contribution to journal › Article
TY - JOUR
T1 - Redox-active organometallic Ir complexes containing biphenyl-2,2′- diyl
AU - Lu, Zheng
AU - Jun, Chul Ho
AU - De Gala, Susan R.
AU - Sigalas, Michel
AU - Eisenstein, Odile
AU - Crabtree, Robert H.
PY - 1993/12/1
Y1 - 1993/12/1
N2 - The redox-active complexes [Ir(PPh3)2(biph)Cl] 3 and [Ir(PMe3)3(biph)Cl] 6 contain biphenyl-2,2-diyl (biph), the organometallic analogue of bipy; 3 shows an unexpected five-coordinate structure lying between T and Y geometry and oxidation of 6 by NOBF4 gives [Ir(PMe3)3(biphBF)Cl]+ (8)+, an unprecedented IrIV boryl complex.
AB - The redox-active complexes [Ir(PPh3)2(biph)Cl] 3 and [Ir(PMe3)3(biph)Cl] 6 contain biphenyl-2,2-diyl (biph), the organometallic analogue of bipy; 3 shows an unexpected five-coordinate structure lying between T and Y geometry and oxidation of 6 by NOBF4 gives [Ir(PMe3)3(biphBF)Cl]+ (8)+, an unprecedented IrIV boryl complex.
UR - http://www.scopus.com/inward/record.url?scp=33745165541&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33745165541&partnerID=8YFLogxK
U2 - 10.1039/C39930001877
DO - 10.1039/C39930001877
M3 - Article
AN - SCOPUS:33745165541
SP - 1877
EP - 1880
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 24
ER -