Redox-active organometallic Ir complexes containing biphenyl-2,2′- diyl

Zheng Lu; Chul Ho Jun; Susan R. De Gala; Michel Sigalas; Odile Eisenstein; Robert H. Crabtree

doi:10.1039/C39930001877

Redox-active organometallic Ir complexes containing biphenyl-2,2′- diyl

Zheng Lu, Chul Ho Jun, Susan R. De Gala, Michel Sigalas, Odile Eisenstein, Robert H. Crabtree

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

The redox-active complexes [Ir(PPh₃)₂(biph)Cl] 3 and [Ir(PMe₃)₃(biph)Cl] 6 contain biphenyl-2,2-diyl (biph), the organometallic analogue of bipy; 3 shows an unexpected five-coordinate structure lying between T and Y geometry and oxidation of 6 by NOBF₄ gives [Ir(PMe₃)₃(biphBF)Cl]⁺ (8)⁺, an unprecedented Ir^IV boryl complex.

Original language	English
Pages (from-to)	1877-1880
Number of pages	4
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/C39930001877
Publication status	Published - 1993

All Science Journal Classification (ASJC) codes

Molecular Medicine

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title = "Redox-active organometallic Ir complexes containing biphenyl-2,2′- diyl",

abstract = "The redox-active complexes [Ir(PPh3)2(biph)Cl] 3 and [Ir(PMe3)3(biph)Cl] 6 contain biphenyl-2,2-diyl (biph), the organometallic analogue of bipy; 3 shows an unexpected five-coordinate structure lying between T and Y geometry and oxidation of 6 by NOBF4 gives [Ir(PMe3)3(biphBF)Cl]+ (8)+, an unprecedented IrIV boryl complex.",

author = "Zheng Lu and Jun, {Chul Ho} and {De Gala}, {Susan R.} and Michel Sigalas and Odile Eisenstein and Crabtree, {Robert H.}",

year = "1993",

doi = "10.1039/C39930001877",

language = "English",

pages = "1877--1880",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Redox-active organometallic Ir complexes containing biphenyl-2,2′- diyl

AU - Lu, Zheng

AU - Jun, Chul Ho

AU - De Gala, Susan R.

AU - Sigalas, Michel

AU - Eisenstein, Odile

AU - Crabtree, Robert H.

PY - 1993

Y1 - 1993

N2 - The redox-active complexes [Ir(PPh3)2(biph)Cl] 3 and [Ir(PMe3)3(biph)Cl] 6 contain biphenyl-2,2-diyl (biph), the organometallic analogue of bipy; 3 shows an unexpected five-coordinate structure lying between T and Y geometry and oxidation of 6 by NOBF4 gives [Ir(PMe3)3(biphBF)Cl]+ (8)+, an unprecedented IrIV boryl complex.

AB - The redox-active complexes [Ir(PPh3)2(biph)Cl] 3 and [Ir(PMe3)3(biph)Cl] 6 contain biphenyl-2,2-diyl (biph), the organometallic analogue of bipy; 3 shows an unexpected five-coordinate structure lying between T and Y geometry and oxidation of 6 by NOBF4 gives [Ir(PMe3)3(biphBF)Cl]+ (8)+, an unprecedented IrIV boryl complex.

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U2 - 10.1039/C39930001877

DO - 10.1039/C39930001877

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EP - 1880

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 24

ER -

Redox-active organometallic Ir complexes containing biphenyl-2,2′- diyl

Abstract

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