Abstract
The redox-active complexes [Ir(PPh3)2(biph)Cl] 3 and [Ir(PMe3)3(biph)Cl] 6 contain biphenyl-2,2-diyl (biph), the organometallic analogue of bipy; 3 shows an unexpected five-coordinate structure lying between T and Y geometry and oxidation of 6 by NOBF4 gives [Ir(PMe3)3(biphBF)Cl]+ (8)+, an unprecedented IrIV boryl complex.
Original language | English |
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Pages (from-to) | 1877-1880 |
Number of pages | 4 |
Journal | Journal of the Chemical Society, Chemical Communications |
Issue number | 24 |
DOIs | |
Publication status | Published - 1993 |
All Science Journal Classification (ASJC) codes
- Molecular Medicine