Reduction Behavior of Dolomite-Fluxed Magnetite: Coke Composite Pellets at 1573 K (1300 °C)

Hyunsik Park, Il Sohn, John Tsalapatis, Veena Sahajwalla

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

High-temperature behavior of magnetite—coke composite pellet fluxed with dolomite was investigated by customized thermogravimetric analyzer (TGA) at 1573 K (1300 °C). The overall reaction was influenced by C/O ratio and dolomite content. The reduction was accelerated by increased amount of dolomite, while the samples with higher C/O ratio showed the improved reduction degree. X-ray diffraction (XRD) pattern of reduced pellet showed the phase changes of the iron oxides. Noticeable iron peaks were observed when the sample reached the final stage of reduction. CO and CO2 gases released from the reaction were measured by Infrared (IR) gas analyzer. Relation between enhanced reducibility of pellets and larger CO gas evolution from the Boudouard reaction was confirmed from the analysis. Compressive strengths were studied for the practical assessment of reduced pellets. Samples with low-reduction degree showed better physical property. Excessive amount of dolomite also deteriorated the integrity of pellets.

Original languageEnglish
Pages (from-to)1109-1118
Number of pages10
JournalMetallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science
Volume49
Issue number3
DOIs
Publication statusPublished - 2018 Jun 1

Bibliographical note

Funding Information:
The research was supported by the Basic Research Project (GP2017-025) of the Korea Institute of Geoscience and Mineral Resources (KIGAM), funded by the Ministry of Science, ICT, and Future Planning of Korea. This work was also supported by the Industrial Strategic technology development program (10044705, Development of a High-Speed Shaft Reduction Technology Using Low-Cost Fe-Containing Process Wastes) funded by the Ministry of Trade, industry & Energy (MI, Korea).

Publisher Copyright:
© 2018, The Author(s).

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Mechanics of Materials
  • Metals and Alloys
  • Materials Chemistry

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