Retrieving aromaticity of dithiadiazuliporphyrin by oxidation: illustration by experimental and theoretical investigation

Young Mo Sung, Natasza Sprutta, Jun Oh Kim, Yun Hee Koo, Lechosław Latos-Grażyński, Dongho Kim

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The photophysical properties of neutral, monocation radical, and dication of dithiadiazuliporphyrin have been examined with a particular focus on their aromaticity. Dithiadiazuliporphyrin exhibits significantly different characteristics depending on its oxidation state. From these features, we could conclude that the aromaticity of dithiadiazuliporphyrin is changed from nonaromatic to aromatic upon oxidation from neutral to monocation radical and dication by Br2.

Original languageEnglish
Pages (from-to)19502-19505
Number of pages4
JournalRSC Advances
Volume7
Issue number32
DOIs
Publication statusPublished - 2017

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

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