Revealing the Role of Oxygen Debris and Functional Groups on the Water Flux and Molecular Separation of Graphene Oxide Membrane: A Combined Experimental and Theoretical Study

Daewoo Kim, Jidon Jang, In Kim, Yoon Tae Nam, Yousung Jung, Hee Tae Jung

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

A combined experimental and molecular dynamics study revealed the role of oxygen debris (ODs) and functional groups on the nanofiltration performance of a graphene oxide (GO) membrane. A NaOH treatment removed ODs adsorbed onto the graphene oxide (DGO). COOH-decorated GO (CGO) was prepared by controlling the oxidation time of Hummer's method, resulting in 45% of carbons with a COOH group. The water permeance of the prepared GO membrane without ODs was 1 order of magnitude greater than that of GO membranes in our experiments: 1.24, 1.59, and 14.7 L m -2 h -1 bar -1 for GO, CGO, and DGO. However, the rejection of dye molecules below 1 nm in size was dramatically reduced without ODs, indicating that ODs play a critical role in rejecting molecules below 1 nm in size because of electrostatic and hydrogen bonding interactions and by narrowing the effective interlayer spacing, as noted in molecular simulations. Additionally, the CGO membrane displayed a similar separation performance compared to common GO membrane mainly decorated with OH and epoxy.

Original languageEnglish
Pages (from-to)17507-17517
Number of pages11
JournalJournal of Physical Chemistry C
Volume122
Issue number30
DOIs
Publication statusPublished - 2018 Aug 2

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debris
Debris
Oxides
Graphene
Functional groups
graphene
Oxygen
Fluxes
membranes
Membranes
oxides
Water
oxygen
water
electrostatic bonding
Nanofiltration
Molecules
rejection
Molecular dynamics

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

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title = "Revealing the Role of Oxygen Debris and Functional Groups on the Water Flux and Molecular Separation of Graphene Oxide Membrane: A Combined Experimental and Theoretical Study",
abstract = "A combined experimental and molecular dynamics study revealed the role of oxygen debris (ODs) and functional groups on the nanofiltration performance of a graphene oxide (GO) membrane. A NaOH treatment removed ODs adsorbed onto the graphene oxide (DGO). COOH-decorated GO (CGO) was prepared by controlling the oxidation time of Hummer's method, resulting in 45{\%} of carbons with a COOH group. The water permeance of the prepared GO membrane without ODs was 1 order of magnitude greater than that of GO membranes in our experiments: 1.24, 1.59, and 14.7 L m -2 h -1 bar -1 for GO, CGO, and DGO. However, the rejection of dye molecules below 1 nm in size was dramatically reduced without ODs, indicating that ODs play a critical role in rejecting molecules below 1 nm in size because of electrostatic and hydrogen bonding interactions and by narrowing the effective interlayer spacing, as noted in molecular simulations. Additionally, the CGO membrane displayed a similar separation performance compared to common GO membrane mainly decorated with OH and epoxy.",
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Revealing the Role of Oxygen Debris and Functional Groups on the Water Flux and Molecular Separation of Graphene Oxide Membrane : A Combined Experimental and Theoretical Study. / Kim, Daewoo; Jang, Jidon; Kim, In; Nam, Yoon Tae; Jung, Yousung; Jung, Hee Tae.

In: Journal of Physical Chemistry C, Vol. 122, No. 30, 02.08.2018, p. 17507-17517.

Research output: Contribution to journalArticle

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