Revolutionizing the FRET-based light emission in core-shell nanostructures via comprehensive activity of surface plasmons

Saji Thomas Kochuveedu, Taehwang Son, Youmin Lee, Minyung Lee, Donghyun Kim, Dong Ha Kim

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25 Citations (Scopus)

Abstract

We demonstrate the surface-plasmon-induced enhancement of Förster resonance energy transfer (FRET)using a model multilayer core-shell nanostructure consisting of an Au core and surrounding FRET pairs, i.e., CdSe quantum dot donors and S101 dye acceptors. The multilayer configuration was demonstrated to exhibit synergistic effects of surface plasmon energy transfer from the metal to the CdSe and plasmon-enhanced FRET from the quantum dots to the dye. With precise control over the distance between the components in the nanostructure, significant improvement in the emission of CdSe was achieved by combined resonance energy transfer and near-field enhancement by the metal, as well as subsequent improvement in the emission of dye induced by the enhanced emission of CdSe. Consequently, the Förster radius was increased to 7.92 nm and the FRET efficiency was improved to 86.57% in the tailored plasmonic FRET nanostructure compared to the conventional FRET system (22.46%) without plasmonic metals.

Original languageEnglish
Article number4735
JournalScientific reports
Volume4
DOIs
Publication statusPublished - 2014 Apr 22

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plasmons
light emission
energy transfer
dyes
quantum dots
metals
augmentation
near fields
radii
configurations

All Science Journal Classification (ASJC) codes

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Kochuveedu, Saji Thomas ; Son, Taehwang ; Lee, Youmin ; Lee, Minyung ; Kim, Donghyun ; Kim, Dong Ha. / Revolutionizing the FRET-based light emission in core-shell nanostructures via comprehensive activity of surface plasmons. In: Scientific reports. 2014 ; Vol. 4.
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Revolutionizing the FRET-based light emission in core-shell nanostructures via comprehensive activity of surface plasmons. / Kochuveedu, Saji Thomas; Son, Taehwang; Lee, Youmin; Lee, Minyung; Kim, Donghyun; Kim, Dong Ha.

In: Scientific reports, Vol. 4, 4735, 22.04.2014.

Research output: Contribution to journalArticle

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AU - Kochuveedu, Saji Thomas

AU - Son, Taehwang

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AB - We demonstrate the surface-plasmon-induced enhancement of Förster resonance energy transfer (FRET)using a model multilayer core-shell nanostructure consisting of an Au core and surrounding FRET pairs, i.e., CdSe quantum dot donors and S101 dye acceptors. The multilayer configuration was demonstrated to exhibit synergistic effects of surface plasmon energy transfer from the metal to the CdSe and plasmon-enhanced FRET from the quantum dots to the dye. With precise control over the distance between the components in the nanostructure, significant improvement in the emission of CdSe was achieved by combined resonance energy transfer and near-field enhancement by the metal, as well as subsequent improvement in the emission of dye induced by the enhanced emission of CdSe. Consequently, the Förster radius was increased to 7.92 nm and the FRET efficiency was improved to 86.57% in the tailored plasmonic FRET nanostructure compared to the conventional FRET system (22.46%) without plasmonic metals.

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