Rh(I)-catalyzed O-silylation of alcohol with vinylsilane

Jung Woo Park, Hoon Jo Chang, Chul Ho Jun

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Silyl ethers can be produced from alcohols and vinylsilanes under a rhodium(I) catalyst. The reaction is believed to proceed through an O-H bond cleavage of alcohol by rhodium(I) complex and a subsequent hydride insertion into vinylsilane followed by β-silyl elimination of the resulting β-silylethyl rhodium(III) complex.

Original languageEnglish
Pages (from-to)771-775
Number of pages5
JournalSynlett
Issue number5
DOIs
Publication statusPublished - 2006 Mar 17

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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