Rh(I)-catalyzed solvent-free ortho-alkylation of aromatic imines under microwave irradiation

Giang Vo-Thanh; Hind Lahrache; André Loupy; In Jung Kim; Duck Ho Chang; Chul Ho Jun

doi:10.1016/j.tet.2004.05.003

Rh(I)-catalyzed solvent-free ortho-alkylation of aromatic imines under microwave irradiation

Giang Vo-Thanh, Hind Lahrache, André Loupy, In Jung Kim, Duck Ho Chang, Chul Ho Jun

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

The synthesis of ortho-alkylated ketones through a chelation-assisted Rh (I) catalyzed ortho-alkylation reaction of aromatic imines under microwave activated solvent-free conditions in monomode reactors was performed. These conditions have been also applied to hydroacylation and ortho-alkylation reactions with aldimines.

Original language	English
Pages (from-to)	5539-5543
Number of pages	5
Journal	Tetrahedron
Volume	60
Issue number	26
DOIs	https://doi.org/10.1016/j.tet.2004.05.003
Publication status	Published - 2004 Jun 21

Bibliographical note

Funding Information:
This work was supported in part by the National Research Laboratory Program (NRL, 2000-N-NL-010C-271) administered by the Ministry of Science and Technology and CBMH. We thank sincerely Dr Renée Paugam (Paris-South University, Laboratoire des Carbocycles) for skilled assistance in theoretical calculations section of the polarity of the transition state.

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tet.2004.05.003

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title = "Rh(I)-catalyzed solvent-free ortho-alkylation of aromatic imines under microwave irradiation",

abstract = "The synthesis of ortho-alkylated ketones through a chelation-assisted Rh (I) catalyzed ortho-alkylation reaction of aromatic imines under microwave activated solvent-free conditions in monomode reactors was performed. These conditions have been also applied to hydroacylation and ortho-alkylation reactions with aldimines.",

author = "Giang Vo-Thanh and Hind Lahrache and Andr{\'e} Loupy and Kim, {In Jung} and Chang, {Duck Ho} and Jun, {Chul Ho}",

note = "Funding Information: This work was supported in part by the National Research Laboratory Program (NRL, 2000-N-NL-010C-271) administered by the Ministry of Science and Technology and CBMH. We thank sincerely Dr Ren{\'e}e Paugam (Paris-South University, Laboratoire des Carbocycles) for skilled assistance in theoretical calculations section of the polarity of the transition state.",

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doi = "10.1016/j.tet.2004.05.003",

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T1 - Rh(I)-catalyzed solvent-free ortho-alkylation of aromatic imines under microwave irradiation

AU - Vo-Thanh, Giang

AU - Lahrache, Hind

AU - Loupy, André

AU - Kim, In Jung

AU - Chang, Duck Ho

AU - Jun, Chul Ho

N1 - Funding Information: This work was supported in part by the National Research Laboratory Program (NRL, 2000-N-NL-010C-271) administered by the Ministry of Science and Technology and CBMH. We thank sincerely Dr Renée Paugam (Paris-South University, Laboratoire des Carbocycles) for skilled assistance in theoretical calculations section of the polarity of the transition state.

PY - 2004/6/21

Y1 - 2004/6/21

N2 - The synthesis of ortho-alkylated ketones through a chelation-assisted Rh (I) catalyzed ortho-alkylation reaction of aromatic imines under microwave activated solvent-free conditions in monomode reactors was performed. These conditions have been also applied to hydroacylation and ortho-alkylation reactions with aldimines.

AB - The synthesis of ortho-alkylated ketones through a chelation-assisted Rh (I) catalyzed ortho-alkylation reaction of aromatic imines under microwave activated solvent-free conditions in monomode reactors was performed. These conditions have been also applied to hydroacylation and ortho-alkylation reactions with aldimines.

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VL - 60

SP - 5539

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JO - Tetrahedron

JF - Tetrahedron

IS - 26

ER -

Rh(I)-catalyzed solvent-free ortho-alkylation of aromatic imines under microwave irradiation

Abstract

Bibliographical note

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