Rh(I)-catalyzed solvent-free ortho-alkylation of aromatic imines under microwave irradiation

Giang Vo-Thanh, Hind Lahrache, André Loupy, In Jung Kim, Duck Ho Chang, Chul Ho Jun

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

The synthesis of ortho-alkylated ketones through a chelation-assisted Rh (I) catalyzed ortho-alkylation reaction of aromatic imines under microwave activated solvent-free conditions in monomode reactors was performed. These conditions have been also applied to hydroacylation and ortho-alkylation reactions with aldimines.

Original languageEnglish
Pages (from-to)5539-5543
Number of pages5
JournalTetrahedron
Volume60
Issue number26
DOIs
Publication statusPublished - 2004 Jun 21

Fingerprint

Imines
Microwave irradiation
Alkylation
Microwaves
Chelation
Ketones

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Vo-Thanh, Giang ; Lahrache, Hind ; Loupy, André ; Kim, In Jung ; Chang, Duck Ho ; Jun, Chul Ho. / Rh(I)-catalyzed solvent-free ortho-alkylation of aromatic imines under microwave irradiation. In: Tetrahedron. 2004 ; Vol. 60, No. 26. pp. 5539-5543.
@article{eb8512badf624b6fbbdf0679f760973b,
title = "Rh(I)-catalyzed solvent-free ortho-alkylation of aromatic imines under microwave irradiation",
abstract = "The synthesis of ortho-alkylated ketones through a chelation-assisted Rh (I) catalyzed ortho-alkylation reaction of aromatic imines under microwave activated solvent-free conditions in monomode reactors was performed. These conditions have been also applied to hydroacylation and ortho-alkylation reactions with aldimines.",
author = "Giang Vo-Thanh and Hind Lahrache and Andr{\'e} Loupy and Kim, {In Jung} and Chang, {Duck Ho} and Jun, {Chul Ho}",
year = "2004",
month = "6",
day = "21",
doi = "10.1016/j.tet.2004.05.003",
language = "English",
volume = "60",
pages = "5539--5543",
journal = "Tetrahedron",
issn = "0040-4020",
publisher = "Elsevier Limited",
number = "26",

}

Rh(I)-catalyzed solvent-free ortho-alkylation of aromatic imines under microwave irradiation. / Vo-Thanh, Giang; Lahrache, Hind; Loupy, André; Kim, In Jung; Chang, Duck Ho; Jun, Chul Ho.

In: Tetrahedron, Vol. 60, No. 26, 21.06.2004, p. 5539-5543.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Rh(I)-catalyzed solvent-free ortho-alkylation of aromatic imines under microwave irradiation

AU - Vo-Thanh, Giang

AU - Lahrache, Hind

AU - Loupy, André

AU - Kim, In Jung

AU - Chang, Duck Ho

AU - Jun, Chul Ho

PY - 2004/6/21

Y1 - 2004/6/21

N2 - The synthesis of ortho-alkylated ketones through a chelation-assisted Rh (I) catalyzed ortho-alkylation reaction of aromatic imines under microwave activated solvent-free conditions in monomode reactors was performed. These conditions have been also applied to hydroacylation and ortho-alkylation reactions with aldimines.

AB - The synthesis of ortho-alkylated ketones through a chelation-assisted Rh (I) catalyzed ortho-alkylation reaction of aromatic imines under microwave activated solvent-free conditions in monomode reactors was performed. These conditions have been also applied to hydroacylation and ortho-alkylation reactions with aldimines.

UR - http://www.scopus.com/inward/record.url?scp=2942555168&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=2942555168&partnerID=8YFLogxK

U2 - 10.1016/j.tet.2004.05.003

DO - 10.1016/j.tet.2004.05.003

M3 - Article

AN - SCOPUS:2942555168

VL - 60

SP - 5539

EP - 5543

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 26

ER -