Rhodamine-based fluorescent probe for sequential detection of Al3+ ions and adenosine monophosphate in water

Rajinder Kaur, Sanjeev Saini, Navneet Kaur, Narinder Singh, Doo Ok Jang

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Organic nanoparticles (N1) were prepared by dispersing thiophene-conjugated rhodamine derivative 1 in a buffer solution (10 mM TRIS, pH 7.4, containing 1% DMSO, v/v). N1 selectively recognized Al3+ ions through the “OFF-ON” switching mechanism of the spirolactam ring in rhodamine. The resulting N1·Al3+ complex recognized the biologically important molecule adenosine monophosphate (AMP) through a cation displacement process with a detection limit of 2 nM. N1 was capable of determining the concentration of Al3+ ions in environmental and biological samples. Portable test strips of N1 were prepared for the recognition of Al3+ ions and AMP for practical uses. Furthermore, it was demonstrated that the N1·Al3+ complex facilitated real-time monitoring of AMP concentration in the hydrolysis of ATP and ADP.

Original languageEnglish
Article number117523
JournalSpectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume225
DOIs
Publication statusPublished - 2020 Jan 15

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Atomic and Molecular Physics, and Optics
  • Instrumentation
  • Spectroscopy

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