Ring opening of naphthenic molecules over metal containing mesoporous Y zeolite catalyst

You Jin Lee, Eun Sang Kim, Tae Wan Kim, Chul Ung Kim, Kwang Eun Jeong, Chang Ha Lee, Soon Yong Jeong

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Mesoporous Y zeolite (Meso-Y) with a uniform mesopore was synthesized via pseudomorphic synthesis. The Meso-Y supported Ni-W catalyst (NiW/Meso-Y) was introduced as a catalyst for the selective ring opening of naphthenic rings. The catalytic test for the ring opening of naphthalene as a model compound of multi-ring aromatics was performed using a batch-type reaction system with both sulfided 20 wt% NiW/Meso-Y and NiW/Y catalysts under different reaction conditions. The catalytic results reveal that the Meso-Y supported NiW catalyst experiences a naphthalene conversion similar to the NiW/Y catalyst, but the NiW/Meso-Y catalyst has higher product yields for BTEX (benzene, toluene, ethyl benzene, and xylene) and the middle distillate than those of the NiW/Y catalyst at a low reaction temperature. These results suggest that the mesoporosity of the NiW/Meso-Y catalyst is more advantageous for the ring opening reaction of multi-ring aromatics due to the easier access for the bulky molecules compared to the NiW/Y catalyst.

Original languageEnglish
Pages (from-to)5334-5337
Number of pages4
JournalJournal of Nanoscience and Nanotechnology
Volume15
Issue number7
DOIs
Publication statusPublished - 2015 Jul 1

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Chemistry(all)
  • Biomedical Engineering
  • Materials Science(all)
  • Condensed Matter Physics

Fingerprint Dive into the research topics of 'Ring opening of naphthenic molecules over metal containing mesoporous Y zeolite catalyst'. Together they form a unique fingerprint.

  • Cite this