Robust Co-catalytic performance of nanodiamonds loaded on WO3 for the decomposition of volatile organic compounds under visible light

Hyoung Il Kim, Hee Na Kim, Seunghyun Weon, Gun Hee Moon, Jae Hong Kim, Wonyong Choi

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Proper co-catalysts (usually noble metals), combined with semiconductor materials, are commonly needed to maximize the efficiency of photocatalysis. Search for cost-effective and practical alternatives for noble-metal co-catalysts is under intense investigation. In this work, nanodiamond (ND), which is a carbon nanomaterial with a unique sp3(core)/sp2(shell) structure, was combined with WO3 (as an alternative co-catalyst for Pt) and applied for the degradation of volatile organic compounds under visible light. NDs-loaded WO3 showed a highly enhanced photocatalytic activity for the degradation of acetaldehyde (∼17 times higher than bare WO) which is more efficient than other well-known co-catalysts (Ag, Pd, Au, and CuO) loaded onto WO3 and comparable to Pt-loaded WO3. Various surface modifications of ND and photoelectochemical measurements revealed that the graphitic carbon shell (sp2) on the diamond core (sp3) plays a crucial role in charge separation and the subsequent interfacial charge transfer. As a result, ND/WO3 showed much higher production of OH radicals than bare WO3 under visible light. Since ND has a highly transparent characteristic, the light shielding that is often problematic with other carbon-based co-catalysts was considerably lower with NDs-loaded WO3. As a result, the photocatalytic activity of NDs/WO3 was higher than that of WO3 loaded with other carbon-based co-catalysts (graphene oxide or reduced graphene oxide). A range of spectroscopic and photo(electro)chemical techniques were systematically employed to investigate the properties of NDs-loaded WO3. ND is proposed as a cost-effective and practical nanomaterial to replace expensive noble-metal co-catalysts.

Original languageEnglish
JournalACS Catalysis
Volume6
Issue number12
DOIs
Publication statusPublished - 2016 Jan 1

Fingerprint

Nanodiamonds
Volatile Organic Compounds
Volatile organic compounds
Decomposition
Catalysts
Carbon
Precious metals
Graphite
Nanostructured materials
Oxides
Graphene
Degradation
Diamond
Acetaldehyde
Photocatalysis
Shielding
Surface treatment
Charge transfer
Costs
Diamonds

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Kim, Hyoung Il ; Kim, Hee Na ; Weon, Seunghyun ; Moon, Gun Hee ; Kim, Jae Hong ; Choi, Wonyong. / Robust Co-catalytic performance of nanodiamonds loaded on WO3 for the decomposition of volatile organic compounds under visible light. In: ACS Catalysis. 2016 ; Vol. 6, No. 12.
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abstract = "Proper co-catalysts (usually noble metals), combined with semiconductor materials, are commonly needed to maximize the efficiency of photocatalysis. Search for cost-effective and practical alternatives for noble-metal co-catalysts is under intense investigation. In this work, nanodiamond (ND), which is a carbon nanomaterial with a unique sp3(core)/sp2(shell) structure, was combined with WO3 (as an alternative co-catalyst for Pt) and applied for the degradation of volatile organic compounds under visible light. NDs-loaded WO3 showed a highly enhanced photocatalytic activity for the degradation of acetaldehyde (∼17 times higher than bare WO) which is more efficient than other well-known co-catalysts (Ag, Pd, Au, and CuO) loaded onto WO3 and comparable to Pt-loaded WO3. Various surface modifications of ND and photoelectochemical measurements revealed that the graphitic carbon shell (sp2) on the diamond core (sp3) plays a crucial role in charge separation and the subsequent interfacial charge transfer. As a result, ND/WO3 showed much higher production of OH radicals than bare WO3 under visible light. Since ND has a highly transparent characteristic, the light shielding that is often problematic with other carbon-based co-catalysts was considerably lower with NDs-loaded WO3. As a result, the photocatalytic activity of NDs/WO3 was higher than that of WO3 loaded with other carbon-based co-catalysts (graphene oxide or reduced graphene oxide). A range of spectroscopic and photo(electro)chemical techniques were systematically employed to investigate the properties of NDs-loaded WO3. ND is proposed as a cost-effective and practical nanomaterial to replace expensive noble-metal co-catalysts.",
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Robust Co-catalytic performance of nanodiamonds loaded on WO3 for the decomposition of volatile organic compounds under visible light. / Kim, Hyoung Il; Kim, Hee Na; Weon, Seunghyun; Moon, Gun Hee; Kim, Jae Hong; Choi, Wonyong.

In: ACS Catalysis, Vol. 6, No. 12, 01.01.2016.

Research output: Contribution to journalArticle

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