Room temperature synthesis routes to the 2D nanoplates and 1D nanowires/nanorods of manganese oxides with highly stable pseudocapacitance behaviors

Da Young Sung, In Young Kim, Tae Woo Kim, Min Sun Song, Seong Ju Hwang

Research output: Contribution to journalArticle

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Abstract

The 2D nanoplates of δ-MnO2 and the 1D nanowires/nanorods of α-MnO2 can be synthesized at room temperature via one-pot oxidation reaction of commercially available divalent manganese compounds. Treating the MnO or MnCO3 precursor with persulfate ions for 1-2 days yields layered δ-MnO2 2D nanoplates, whereas the same oxidation reaction for the MnSO4 precursor produces γ-MnO 2-structured 3D urchins. As the reaction time is extended for ∼14-21 days, not only δ-MnO2 nanoplates but also γ-MnO2 urchins are changed to wellseparated 1D nanostructured α-MnO2 materials with controllable diameters. According to N2 adsorption-desorption isotherm measurements and Mn K-edge X-ray absorption spectroscopy, all the obtained manganate nanostructures show expanded surface areas of ∼50-120 m2 g-1 and the mixed oxidation state of Mn3+/Mn4+, respectively. All the present nanostructured manganese oxides exhibit pseudocapacitance behaviors with large specific capacitance and excellent capacitance retention, highlighting their promising functionality as a supercapacitor electrode. Among the materials under investigation, the δ-MnO2 2D nanoplates show the largest specific capacitance (∼180-210 F g-1). The present finding clearly demonstrates that the room-temperature oxidation reaction of the MnO orMnCO3 precursor can provide a facile soft-chemical route to 2D δ-MnO2 nanoplates and 1D R-MnO2 nanowires/nanorods with highly stable pseudocapacitance behaviors.

Original languageEnglish
Pages (from-to)13171-13179
Number of pages9
JournalJournal of Physical Chemistry C
Volume115
Issue number27
DOIs
Publication statusPublished - 2011 Jul 14

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Manganese oxide
manganese oxides
Nanorods
nanorods
Nanowires
nanowires
routes
Oxidation
oxidation
Capacitance
capacitance
room temperature
synthesis
Manganese Compounds
Manganese compounds
manganese compounds
Temperature
X ray absorption spectroscopy
electrochemical capacitors
Nanostructured materials

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

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title = "Room temperature synthesis routes to the 2D nanoplates and 1D nanowires/nanorods of manganese oxides with highly stable pseudocapacitance behaviors",
abstract = "The 2D nanoplates of δ-MnO2 and the 1D nanowires/nanorods of α-MnO2 can be synthesized at room temperature via one-pot oxidation reaction of commercially available divalent manganese compounds. Treating the MnO or MnCO3 precursor with persulfate ions for 1-2 days yields layered δ-MnO2 2D nanoplates, whereas the same oxidation reaction for the MnSO4 precursor produces γ-MnO 2-structured 3D urchins. As the reaction time is extended for ∼14-21 days, not only δ-MnO2 nanoplates but also γ-MnO2 urchins are changed to wellseparated 1D nanostructured α-MnO2 materials with controllable diameters. According to N2 adsorption-desorption isotherm measurements and Mn K-edge X-ray absorption spectroscopy, all the obtained manganate nanostructures show expanded surface areas of ∼50-120 m2 g-1 and the mixed oxidation state of Mn3+/Mn4+, respectively. All the present nanostructured manganese oxides exhibit pseudocapacitance behaviors with large specific capacitance and excellent capacitance retention, highlighting their promising functionality as a supercapacitor electrode. Among the materials under investigation, the δ-MnO2 2D nanoplates show the largest specific capacitance (∼180-210 F g-1). The present finding clearly demonstrates that the room-temperature oxidation reaction of the MnO orMnCO3 precursor can provide a facile soft-chemical route to 2D δ-MnO2 nanoplates and 1D R-MnO2 nanowires/nanorods with highly stable pseudocapacitance behaviors.",
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Room temperature synthesis routes to the 2D nanoplates and 1D nanowires/nanorods of manganese oxides with highly stable pseudocapacitance behaviors. / Sung, Da Young; Kim, In Young; Kim, Tae Woo; Song, Min Sun; Hwang, Seong Ju.

In: Journal of Physical Chemistry C, Vol. 115, No. 27, 14.07.2011, p. 13171-13179.

Research output: Contribution to journalArticle

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T1 - Room temperature synthesis routes to the 2D nanoplates and 1D nanowires/nanorods of manganese oxides with highly stable pseudocapacitance behaviors

AU - Sung, Da Young

AU - Kim, In Young

AU - Kim, Tae Woo

AU - Song, Min Sun

AU - Hwang, Seong Ju

PY - 2011/7/14

Y1 - 2011/7/14

N2 - The 2D nanoplates of δ-MnO2 and the 1D nanowires/nanorods of α-MnO2 can be synthesized at room temperature via one-pot oxidation reaction of commercially available divalent manganese compounds. Treating the MnO or MnCO3 precursor with persulfate ions for 1-2 days yields layered δ-MnO2 2D nanoplates, whereas the same oxidation reaction for the MnSO4 precursor produces γ-MnO 2-structured 3D urchins. As the reaction time is extended for ∼14-21 days, not only δ-MnO2 nanoplates but also γ-MnO2 urchins are changed to wellseparated 1D nanostructured α-MnO2 materials with controllable diameters. According to N2 adsorption-desorption isotherm measurements and Mn K-edge X-ray absorption spectroscopy, all the obtained manganate nanostructures show expanded surface areas of ∼50-120 m2 g-1 and the mixed oxidation state of Mn3+/Mn4+, respectively. All the present nanostructured manganese oxides exhibit pseudocapacitance behaviors with large specific capacitance and excellent capacitance retention, highlighting their promising functionality as a supercapacitor electrode. Among the materials under investigation, the δ-MnO2 2D nanoplates show the largest specific capacitance (∼180-210 F g-1). The present finding clearly demonstrates that the room-temperature oxidation reaction of the MnO orMnCO3 precursor can provide a facile soft-chemical route to 2D δ-MnO2 nanoplates and 1D R-MnO2 nanowires/nanorods with highly stable pseudocapacitance behaviors.

AB - The 2D nanoplates of δ-MnO2 and the 1D nanowires/nanorods of α-MnO2 can be synthesized at room temperature via one-pot oxidation reaction of commercially available divalent manganese compounds. Treating the MnO or MnCO3 precursor with persulfate ions for 1-2 days yields layered δ-MnO2 2D nanoplates, whereas the same oxidation reaction for the MnSO4 precursor produces γ-MnO 2-structured 3D urchins. As the reaction time is extended for ∼14-21 days, not only δ-MnO2 nanoplates but also γ-MnO2 urchins are changed to wellseparated 1D nanostructured α-MnO2 materials with controllable diameters. According to N2 adsorption-desorption isotherm measurements and Mn K-edge X-ray absorption spectroscopy, all the obtained manganate nanostructures show expanded surface areas of ∼50-120 m2 g-1 and the mixed oxidation state of Mn3+/Mn4+, respectively. All the present nanostructured manganese oxides exhibit pseudocapacitance behaviors with large specific capacitance and excellent capacitance retention, highlighting their promising functionality as a supercapacitor electrode. Among the materials under investigation, the δ-MnO2 2D nanoplates show the largest specific capacitance (∼180-210 F g-1). The present finding clearly demonstrates that the room-temperature oxidation reaction of the MnO orMnCO3 precursor can provide a facile soft-chemical route to 2D δ-MnO2 nanoplates and 1D R-MnO2 nanowires/nanorods with highly stable pseudocapacitance behaviors.

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