Graphene nanomeshes (GNMs) with nanoscale periodic or quasi-periodic nanoholes have attracted considerable interest because of unique features such as their open energy band gap, enlarged specific surface area, and high optical transmittance. These features are useful for applications in semiconducting devices, photocatalysis, sensors, and energy-related systems. Here, we report on the facile and scalable preparation of multifunctional micron-scale GNMs with high-density of nanoperforations by catalytic carbon gasification. The catalytic carbon gasification process induces selective decomposition on the graphene adjacent to the metal catalyst, thus forming nanoperforations. The pore size, pore density distribution, and neck size of the GNMs can be controlled by adjusting the size and fraction of the metal oxide on graphene. The fabricated GNM electrodes exhibit superior electrochemical properties for supercapacitor (ultracapacitor) applications, including exceptionally high capacitance (253 F g-1 at 1 A g-1) and high rate capability (212 F g-1 at 100 A g-1) with excellent cycle stability (91% of the initial capacitance after 50000 charge/discharge cycles). Further, the edge-enriched structure of GNMs plays an important role in achieving edge-selected and high-level nitrogen doping.
Bibliographical noteFunding Information:
This work was supported by Energy Efficiency & Resources program of the Korea Institute of Energy Technology Evaluation Planning (KETEP), and was granted financial resources from the Ministry of Trade, Industry & Energy, Republic of Korea (No. 20122010100140) and (No. 20152020105770). This research was supported by a grant from the Technology Development Program for Strategic Core Materials funded by the Ministry of Trade, Industry & Energy, Republic of Korea (Project No. 10047758). This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT & Future Planning (2015R1A2A2A03006633). This work was supported by a grant from the Fundamental R&D program and funded by the Korea Institute of Ceramic Engineering and Technology (KICET) and Ministry of Trade, Industry and Energy (MOTIE), Republic of Korea. This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2015R1A6A3A03018844). The work performed at the Brookhaven National Laboratory was supported by the Assistant Secretary for the Energy Efficiency and Renewable Energy Office, Vehicle Technology, of the U. S. Department of Energy (DOE), under contract no. DE-SC0012704. Canadian Light Source is supported by the Canada Foundation for Innovation, the Natural Sciences and Engineering Research Council of Canada (NSERC), the University of Saskatchewan, the Government of Saskatchewan, Western Economic Diversification Canada, the National Research Council Canada, and the Canadian Institutes of Health Research. We greatly thank the kind help from Dr. Tom Regier, beamline scientist at the SGM beamline at the CLS.
All Science Journal Classification (ASJC) codes
- Environmental Chemistry
- Renewable Energy, Sustainability and the Environment
- Nuclear Energy and Engineering