Selective Ion Transporting Polymerized Ionic Liquid Membrane Separator for Enhancing Cycle Stability and Durability in Secondary Zinc-Air Battery Systems

Ho Jung Hwang, Won Seok Chi, Ohchan Kwon, Jin Goo Lee, Jong Hak Kim, Yong-Gun Shul

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Rechargeable secondary zinc-air batteries with superior cyclic stability were developed using commercial polypropylene (PP) membrane coated with polymerized ionic liquid as separators. The anionic exchange polymer was synthesized copolymerizing 1-[(4-ethenylphenyl)methyl]-3-butylimidazolium hydroxide (EBIH) and butyl methacrylate (BMA) monomers by free radical polymerization for both functionality and structural integrity. The ionic liquid induced copolymer was coated on a commercially available PP membrane (Celguard 5550). The coat allows anionic transfer through the separator and minimizes the migration of zincate ions to the cathode compartment, which reduces electrolyte conductivity and may deteriorate catalytic activity by the formation of zinc oxide on the surface of the catalyst layer. Energy dispersive X-ray spectroscopy (EDS) data revealed the copolymer-coated separator showed less zinc element in the cathode, indicating lower zinc crossover through the membrane. Ion coupled plasma optical emission spectroscopy (ICP-OES) analysis confirmed over 96% of zincate ion crossover was reduced. In our charge/discharge setup, the constructed cell with the ionic liquid induced copolymer casted separator exhibited drastically improved durability as the battery life increased more than 281% compared to the pure commercial PP membrane. Electrochemical impedance spectroscopy (EIS) during the cycle process elucidated the premature failure of cells due to the zinc crossover for the untreated cell and revealed a substantial importance must be placed in zincate control.

Original languageEnglish
Pages (from-to)26298-26308
Number of pages11
JournalACS Applied Materials and Interfaces
Volume8
Issue number39
DOIs
Publication statusPublished - 2016 Oct 5

Fingerprint

Ionic Liquids
Liquid membranes
Separators
Ionic liquids
Zinc
Polypropylenes
Durability
Ions
Membranes
Copolymers
Air
Cathodes
Zinc Oxide
Optical emission spectroscopy
Structural integrity
Free radical polymerization
Zinc oxide
Electrochemical impedance spectroscopy
Discharge (fluid mechanics)
Electrolytes

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

@article{05230a38a0b2491781d3904303226f5e,
title = "Selective Ion Transporting Polymerized Ionic Liquid Membrane Separator for Enhancing Cycle Stability and Durability in Secondary Zinc-Air Battery Systems",
abstract = "Rechargeable secondary zinc-air batteries with superior cyclic stability were developed using commercial polypropylene (PP) membrane coated with polymerized ionic liquid as separators. The anionic exchange polymer was synthesized copolymerizing 1-[(4-ethenylphenyl)methyl]-3-butylimidazolium hydroxide (EBIH) and butyl methacrylate (BMA) monomers by free radical polymerization for both functionality and structural integrity. The ionic liquid induced copolymer was coated on a commercially available PP membrane (Celguard 5550). The coat allows anionic transfer through the separator and minimizes the migration of zincate ions to the cathode compartment, which reduces electrolyte conductivity and may deteriorate catalytic activity by the formation of zinc oxide on the surface of the catalyst layer. Energy dispersive X-ray spectroscopy (EDS) data revealed the copolymer-coated separator showed less zinc element in the cathode, indicating lower zinc crossover through the membrane. Ion coupled plasma optical emission spectroscopy (ICP-OES) analysis confirmed over 96{\%} of zincate ion crossover was reduced. In our charge/discharge setup, the constructed cell with the ionic liquid induced copolymer casted separator exhibited drastically improved durability as the battery life increased more than 281{\%} compared to the pure commercial PP membrane. Electrochemical impedance spectroscopy (EIS) during the cycle process elucidated the premature failure of cells due to the zinc crossover for the untreated cell and revealed a substantial importance must be placed in zincate control.",
author = "Hwang, {Ho Jung} and Chi, {Won Seok} and Ohchan Kwon and Lee, {Jin Goo} and Kim, {Jong Hak} and Yong-Gun Shul",
year = "2016",
month = "10",
day = "5",
doi = "10.1021/acsami.6b07841",
language = "English",
volume = "8",
pages = "26298--26308",
journal = "ACS applied materials & interfaces",
issn = "1944-8244",
publisher = "American Chemical Society",
number = "39",

}

Selective Ion Transporting Polymerized Ionic Liquid Membrane Separator for Enhancing Cycle Stability and Durability in Secondary Zinc-Air Battery Systems. / Hwang, Ho Jung; Chi, Won Seok; Kwon, Ohchan; Lee, Jin Goo; Kim, Jong Hak; Shul, Yong-Gun.

In: ACS Applied Materials and Interfaces, Vol. 8, No. 39, 05.10.2016, p. 26298-26308.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Selective Ion Transporting Polymerized Ionic Liquid Membrane Separator for Enhancing Cycle Stability and Durability in Secondary Zinc-Air Battery Systems

AU - Hwang, Ho Jung

AU - Chi, Won Seok

AU - Kwon, Ohchan

AU - Lee, Jin Goo

AU - Kim, Jong Hak

AU - Shul, Yong-Gun

PY - 2016/10/5

Y1 - 2016/10/5

N2 - Rechargeable secondary zinc-air batteries with superior cyclic stability were developed using commercial polypropylene (PP) membrane coated with polymerized ionic liquid as separators. The anionic exchange polymer was synthesized copolymerizing 1-[(4-ethenylphenyl)methyl]-3-butylimidazolium hydroxide (EBIH) and butyl methacrylate (BMA) monomers by free radical polymerization for both functionality and structural integrity. The ionic liquid induced copolymer was coated on a commercially available PP membrane (Celguard 5550). The coat allows anionic transfer through the separator and minimizes the migration of zincate ions to the cathode compartment, which reduces electrolyte conductivity and may deteriorate catalytic activity by the formation of zinc oxide on the surface of the catalyst layer. Energy dispersive X-ray spectroscopy (EDS) data revealed the copolymer-coated separator showed less zinc element in the cathode, indicating lower zinc crossover through the membrane. Ion coupled plasma optical emission spectroscopy (ICP-OES) analysis confirmed over 96% of zincate ion crossover was reduced. In our charge/discharge setup, the constructed cell with the ionic liquid induced copolymer casted separator exhibited drastically improved durability as the battery life increased more than 281% compared to the pure commercial PP membrane. Electrochemical impedance spectroscopy (EIS) during the cycle process elucidated the premature failure of cells due to the zinc crossover for the untreated cell and revealed a substantial importance must be placed in zincate control.

AB - Rechargeable secondary zinc-air batteries with superior cyclic stability were developed using commercial polypropylene (PP) membrane coated with polymerized ionic liquid as separators. The anionic exchange polymer was synthesized copolymerizing 1-[(4-ethenylphenyl)methyl]-3-butylimidazolium hydroxide (EBIH) and butyl methacrylate (BMA) monomers by free radical polymerization for both functionality and structural integrity. The ionic liquid induced copolymer was coated on a commercially available PP membrane (Celguard 5550). The coat allows anionic transfer through the separator and minimizes the migration of zincate ions to the cathode compartment, which reduces electrolyte conductivity and may deteriorate catalytic activity by the formation of zinc oxide on the surface of the catalyst layer. Energy dispersive X-ray spectroscopy (EDS) data revealed the copolymer-coated separator showed less zinc element in the cathode, indicating lower zinc crossover through the membrane. Ion coupled plasma optical emission spectroscopy (ICP-OES) analysis confirmed over 96% of zincate ion crossover was reduced. In our charge/discharge setup, the constructed cell with the ionic liquid induced copolymer casted separator exhibited drastically improved durability as the battery life increased more than 281% compared to the pure commercial PP membrane. Electrochemical impedance spectroscopy (EIS) during the cycle process elucidated the premature failure of cells due to the zinc crossover for the untreated cell and revealed a substantial importance must be placed in zincate control.

UR - http://www.scopus.com/inward/record.url?scp=84990217153&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84990217153&partnerID=8YFLogxK

U2 - 10.1021/acsami.6b07841

DO - 10.1021/acsami.6b07841

M3 - Article

AN - SCOPUS:84990217153

VL - 8

SP - 26298

EP - 26308

JO - ACS applied materials & interfaces

JF - ACS applied materials & interfaces

SN - 1944-8244

IS - 39

ER -