Self-assembled Li3V2(PO4)3/reduced graphene oxide multilayer composite prepared by sequential adsorption

Myeong Seong Kim, Seong Min Bak, Suk Woo Lee, Byung Won Cho, Kwang Chul Roh, Kwang Bum Kim

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Herein, we report on Li3V2(PO4)3 (LVP)/reduced graphene oxide (rGO) multilayer composites prepared via a sequential adsorption method and subsequent heat treatment, and their use as cathodes for high-rate lithium-ion batteries. The sequential adsorption process includes adsorbing oppositely charged components of anionic inorganic species and cationic head of a surfactant adsorbed to graphite oxide sheets, which is a key step in the fabrication of the LVP/rGO multilayer composites. The multilayer structure has open channels between the highly conductive rGO layers while achieving a relatively high tap density, which could effectively improve the rate capability. Consequently, the LVP/rGO multilayer composites exhibit a high tap density (0.6 g cm−3) and good electrochemical properties. Specifically, in the voltage range of 3.0–4.3 V, the composite exhibits a specific capacity of 131 mAh g−1 at 0.1C, a good rate capabilities (88% capacity retention at 60C), and long cycling performance (97% capacity retention after 500 cycles at 10C). Moreover, in the extended voltage range of 3.0–4.8 V, it exhibits a high specific capacity of 185 mAh g−1 at 0.2C, a good rate capability (66% capacity retention at 30C), and stable cycling performance (96% capacity retention after 500 cycles at 10C).

Original languageEnglish
Pages (from-to)167-176
Number of pages10
JournalJournal of Power Sources
Volume367
DOIs
Publication statusPublished - 2017 Jan 1

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Graphite
Oxides
Graphene
graphene
Multilayers
Adsorption
adsorption
composite materials
oxides
Composite materials
cycles
taps
Electric potential
Electrochemical properties
Surface-Active Agents
electric potential
Cathodes
Surface active agents
laminates
Heat treatment

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

Cite this

Kim, Myeong Seong ; Bak, Seong Min ; Lee, Suk Woo ; Cho, Byung Won ; Roh, Kwang Chul ; Kim, Kwang Bum. / Self-assembled Li3V2(PO4)3/reduced graphene oxide multilayer composite prepared by sequential adsorption. In: Journal of Power Sources. 2017 ; Vol. 367. pp. 167-176.
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Self-assembled Li3V2(PO4)3/reduced graphene oxide multilayer composite prepared by sequential adsorption. / Kim, Myeong Seong; Bak, Seong Min; Lee, Suk Woo; Cho, Byung Won; Roh, Kwang Chul; Kim, Kwang Bum.

In: Journal of Power Sources, Vol. 367, 01.01.2017, p. 167-176.

Research output: Contribution to journalArticle

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