Abstract
Self-assembly (SA) is the process in which a system's components - be it molecules, polymers, colloids, or macroscopic particles - organize into ordered and/or functional structures without human intervention. The main challenge in SA research is the ability to "program" the properties of the individual pieces such that they organize into a desired structure. Although a general strategy for doing so is still elusive, heuristic rules can be formulated that guide design of SA under various conditions and thermodynamic constraints. This Review examines SA in both the equilibrium and non-equilibrium/dynamic systems and discusses different SA modalities: energy driven, entropy-driven, templated, and field-directed. Non-equilibrium SA is discussed as a route to reconfigurable ("adaptive") materials, and its connection to biological systems is emphasized.
| Original language | English |
|---|---|
| Pages (from-to) | 1110-1128 |
| Number of pages | 19 |
| Journal | Soft Matter |
| Volume | 5 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - 2009 Mar 19 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Condensed Matter Physics
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Self-assembly : From crystals to cells. / Grzybowski, Bartosz A.; Wilmer, Christopher E.; Kim, Jiwon; Browne, Kevin P.; Bishop, Kyle J.M.
In: Soft Matter, Vol. 5, No. 6, 19.03.2009, p. 1110-1128.Research output: Contribution to journal › Article
TY - JOUR
T1 - Self-assembly
T2 - From crystals to cells
AU - Grzybowski, Bartosz A.
AU - Wilmer, Christopher E.
AU - Kim, Jiwon
AU - Browne, Kevin P.
AU - Bishop, Kyle J.M.
PY - 2009/3/19
Y1 - 2009/3/19
N2 - Self-assembly (SA) is the process in which a system's components - be it molecules, polymers, colloids, or macroscopic particles - organize into ordered and/or functional structures without human intervention. The main challenge in SA research is the ability to "program" the properties of the individual pieces such that they organize into a desired structure. Although a general strategy for doing so is still elusive, heuristic rules can be formulated that guide design of SA under various conditions and thermodynamic constraints. This Review examines SA in both the equilibrium and non-equilibrium/dynamic systems and discusses different SA modalities: energy driven, entropy-driven, templated, and field-directed. Non-equilibrium SA is discussed as a route to reconfigurable ("adaptive") materials, and its connection to biological systems is emphasized.
AB - Self-assembly (SA) is the process in which a system's components - be it molecules, polymers, colloids, or macroscopic particles - organize into ordered and/or functional structures without human intervention. The main challenge in SA research is the ability to "program" the properties of the individual pieces such that they organize into a desired structure. Although a general strategy for doing so is still elusive, heuristic rules can be formulated that guide design of SA under various conditions and thermodynamic constraints. This Review examines SA in both the equilibrium and non-equilibrium/dynamic systems and discusses different SA modalities: energy driven, entropy-driven, templated, and field-directed. Non-equilibrium SA is discussed as a route to reconfigurable ("adaptive") materials, and its connection to biological systems is emphasized.
UR - http://www.scopus.com/inward/record.url?scp=62249167998&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=62249167998&partnerID=8YFLogxK
U2 - 10.1039/b819321p
DO - 10.1039/b819321p
M3 - Article
VL - 5
SP - 1110
EP - 1128
JO - Soft Matter
JF - Soft Matter
SN - 1744-683X
IS - 6
ER -