Self-assembly of metal-organometallic coordination networks

Moonhyun Oh, Gene B. Carpenter, Dwight A. Sweigart

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A range of neutral metal-organometallic coordination networks (MOMNs) containing both backbone and pendant metal sites have been synthesized and characterized. These materials consist of metal ions or metal ion clusters as nodes that are linked by the bifunctional "organometalloligand" (η4-benzoquinone)Mn(CO)3-, which binds through the quinone oxygen atoms. The resulting MOMNs can be rationally designed to a significant extent based upon a knowledge of the electronic and geometrical requirements of the metal ion nodes, the solvent, organometalloligand substituents, and the presence or absence of organic spacers. An impressive range of architectures have been accessed in this manner, suggesting that the use of π-organometallics in coordination directed self-assembly holds much promise.

Original languageEnglish
Pages (from-to)101-112
Number of pages12
JournalMacromolecular Symposia
Volume196
DOIs
Publication statusPublished - 2003 Jul 1

Fingerprint

Organometallics
Self assembly
Metal ions
self assembly
metal ions
Metals
quinones
metals
Carbon Monoxide
spacers
oxygen atoms
Oxygen
Atoms
requirements
electronics
ions
benzoquinone

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

Cite this

Oh, Moonhyun ; Carpenter, Gene B. ; Sweigart, Dwight A. / Self-assembly of metal-organometallic coordination networks. In: Macromolecular Symposia. 2003 ; Vol. 196. pp. 101-112.
@article{0faaa3ab93af438fac74c7b6ebd96763,
title = "Self-assembly of metal-organometallic coordination networks",
abstract = "A range of neutral metal-organometallic coordination networks (MOMNs) containing both backbone and pendant metal sites have been synthesized and characterized. These materials consist of metal ions or metal ion clusters as nodes that are linked by the bifunctional {"}organometalloligand{"} (η4-benzoquinone)Mn(CO)3-, which binds through the quinone oxygen atoms. The resulting MOMNs can be rationally designed to a significant extent based upon a knowledge of the electronic and geometrical requirements of the metal ion nodes, the solvent, organometalloligand substituents, and the presence or absence of organic spacers. An impressive range of architectures have been accessed in this manner, suggesting that the use of π-organometallics in coordination directed self-assembly holds much promise.",
author = "Moonhyun Oh and Carpenter, {Gene B.} and Sweigart, {Dwight A.}",
year = "2003",
month = "7",
day = "1",
doi = "10.1002/masy.200390151",
language = "English",
volume = "196",
pages = "101--112",
journal = "Macromolecular Symposia",
issn = "1022-1360",
publisher = "Wiley-VCH Verlag",

}

Self-assembly of metal-organometallic coordination networks. / Oh, Moonhyun; Carpenter, Gene B.; Sweigart, Dwight A.

In: Macromolecular Symposia, Vol. 196, 01.07.2003, p. 101-112.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Self-assembly of metal-organometallic coordination networks

AU - Oh, Moonhyun

AU - Carpenter, Gene B.

AU - Sweigart, Dwight A.

PY - 2003/7/1

Y1 - 2003/7/1

N2 - A range of neutral metal-organometallic coordination networks (MOMNs) containing both backbone and pendant metal sites have been synthesized and characterized. These materials consist of metal ions or metal ion clusters as nodes that are linked by the bifunctional "organometalloligand" (η4-benzoquinone)Mn(CO)3-, which binds through the quinone oxygen atoms. The resulting MOMNs can be rationally designed to a significant extent based upon a knowledge of the electronic and geometrical requirements of the metal ion nodes, the solvent, organometalloligand substituents, and the presence or absence of organic spacers. An impressive range of architectures have been accessed in this manner, suggesting that the use of π-organometallics in coordination directed self-assembly holds much promise.

AB - A range of neutral metal-organometallic coordination networks (MOMNs) containing both backbone and pendant metal sites have been synthesized and characterized. These materials consist of metal ions or metal ion clusters as nodes that are linked by the bifunctional "organometalloligand" (η4-benzoquinone)Mn(CO)3-, which binds through the quinone oxygen atoms. The resulting MOMNs can be rationally designed to a significant extent based upon a knowledge of the electronic and geometrical requirements of the metal ion nodes, the solvent, organometalloligand substituents, and the presence or absence of organic spacers. An impressive range of architectures have been accessed in this manner, suggesting that the use of π-organometallics in coordination directed self-assembly holds much promise.

UR - http://www.scopus.com/inward/record.url?scp=0041845344&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0041845344&partnerID=8YFLogxK

U2 - 10.1002/masy.200390151

DO - 10.1002/masy.200390151

M3 - Article

AN - SCOPUS:0041845344

VL - 196

SP - 101

EP - 112

JO - Macromolecular Symposia

JF - Macromolecular Symposia

SN - 1022-1360

ER -