Self-assembly of rotaxane-like complexes with macrocycles containing reversible coordinate bonds

Kyu Sung Jeong, Jeung Soon Choi, Sung Youn Chang, Hong Young Chang

Research output: Contribution to journalArticle

48 Citations (Scopus)

Abstract

Supramolecular hydrogen bonds between dumbbell-shaped molecules and macrocycles containing Os(VI)-N coordinate bonds led to spontaneous assembly of rotaxane-like complexes (see picture). As a result of the reversible nature of the Os(VI)-N bonds, the ratio of the free species to the rotaxane- like complex could be precisely controlled in solution by varying the concentrations of the two components.

Original languageEnglish
Pages (from-to)1692-1695
Number of pages4
JournalAngewandte Chemie - International Edition
Volume39
Issue number9
DOIs
Publication statusPublished - 2000 May 2

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Rotaxanes
Self assembly
Hydrogen bonds
Molecules

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Jeong, Kyu Sung ; Choi, Jeung Soon ; Chang, Sung Youn ; Chang, Hong Young. / Self-assembly of rotaxane-like complexes with macrocycles containing reversible coordinate bonds. In: Angewandte Chemie - International Edition. 2000 ; Vol. 39, No. 9. pp. 1692-1695.
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Self-assembly of rotaxane-like complexes with macrocycles containing reversible coordinate bonds. / Jeong, Kyu Sung; Choi, Jeung Soon; Chang, Sung Youn; Chang, Hong Young.

In: Angewandte Chemie - International Edition, Vol. 39, No. 9, 02.05.2000, p. 1692-1695.

Research output: Contribution to journalArticle

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