Self-assembly using organometalloligands as spacers in the controlled formation of isomeric 1D and 2D supramolecular quinonoid networks

Moonhyun Oh, Gene B. Carpenter, Dwight A. Sweigart

Research output: Contribution to journalArticle

53 Citations (Scopus)

Abstract

The concentration of metal ions influences the structural characteristics of self-assembled coordination polymers constructed from Mn2+ ions and [(η4-benzoquinone)Mn(CO)3]- ions. At very low metal-ion concentrations, 1D "string" formations are obtained (see picture), while at higher concentrations, 2D "grid" networks are formed.

Original languageEnglish
Pages (from-to)3650-3653
Number of pages4
JournalAngewandte Chemie - International Edition
Volume41
Issue number19
DOIs
Publication statusPublished - 2002 Oct 4

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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