Self-standing, binder-free electrospun Co3O4/carbon nanofiber composites for non-aqueous Li-air batteries

Myeong Jun Song, Il To Kim, Young Bok Kim, Moo Whan Shin

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

In this study, self-standing, binder-free ZIF-9 derived Co3O4/carbon nanofiber composites were synthesized via electrospinning and post thermal treatment for use as the cathode in a non-aqueous Li-air battery. Due to possessing a three-dimensional cross-linked web structure, Co3O4/carbon nanofiber composites are used directly as the cathode for Li-air batteries without the use of any binders or conductive metal foam, thus alleviating undesirable chemical reactions. We confirm that metallic cobalt (Co) in ZIF-9 is successfully oxidized to cobalt oxide (Co3O4) following two thermal treatment steps by analysis of XRD and XPS. The initial discharge capacity of Co3O4/carbon nanofiber composites exceeds 760 mAh g-1, which is a much higher discharge capacity compared to pristine carbon nanofiber (72 mAh g-1). Additionally, Co3O4/carbon nanofiber composite based cells exhibit improved cycling properties and a lower charge overpotential at various current densities. The improved electrochemical properties of the Co3O4/carbon nanofiber composites are attributed to the catalytic activity and stable contact with the homogeneously distributed Co3O4 in the carbon nanofiber structure. This work demonstrates that the synthesized Co3O4/carbon nanofiber composites could possibly be applied for use as next generation electrode materials for energy storage and conversion devices, particularly Li-air batteries.

Original languageEnglish
Pages (from-to)289-296
Number of pages8
JournalElectrochimica Acta
Volume182
DOIs
Publication statusPublished - 2015 Nov 10

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Electrochemistry

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