Self-standing Co2.4Sn0.6O4 nano rods as high performance anode materials for sodium-ion battery and investigation on its reaction mechanism

Ghulam Ali; Mobinul Islam; Deu S. Bhange; Young Hwa Jung; Mingyuan Ge; Yong S. Chu; Kyung Wan Nam; Yonghua Du; Xiao Qing Yang; Hun Gi Jung; Seong Min Bak; Kyung Yoon Chung

doi:10.1016/j.cej.2022.135791

Self-standing Co_2.4Sn_0.6O₄ nano rods as high performance anode materials for sodium-ion battery and investigation on its reaction mechanism

Ghulam Ali, Mobinul Islam, Deu S. Bhange, Young Hwa Jung, Mingyuan Ge, Yong S. Chu, Kyung Wan Nam, Yonghua Du, Xiao Qing Yang, Hun Gi Jung, Seong Min Bak, Kyung Yoon Chung

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

The self-standing nanorod Co_2.4Sn_0.6O₄ is synthesized as a high-performance anode material in search of high capacity and stable anode materials for sodium-ion batteries. The Co_2.4Sn_0.6O₄ nanorod exhibits a high reversible capacity of 576 mAh g⁻¹ at a current density of 80 mA g⁻¹ and shows excellent high-rate capability. The X-ray absorption spectroscopy study reveals the mechanisms of charge storage reaction and improved cycling performance of Co_2.4Sn_0.6O₄. A partially limited conversion reaction of Co– and Sn-oxide during the cycling effectively regulate the irreversible capacity loss over the cycling that is commonly observed from the conversion and alloying reaction-based anode materials. Furthermore, Co_2.4Sn_0.6O₄ also exhibits superior sodium-ion full cell performance when coupled with a NaNi_2/3Bi_1/3O₂ cathode, demonstrating an energy density of 262 Wh kg⁻¹.

Original language	English
Article number	135791
Journal	Chemical Engineering Journal
Volume	439
DOIs	https://doi.org/10.1016/j.cej.2022.135791
Publication status	Published - 2022 Jul 1

Bibliographical note

Funding Information:
The work doen at KIST was supported by Nano-Material Technology Program (NRF-2020M3H4A3081889) of the National Research Foundation (NRF) funded by the Ministry of Science & ICT and KIST Institutional Program (No. 2E31860). Xiao-Qing Yang at the Brookhaven National Lab was supported by the U.S. Department of Energy, the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies, through the Advanced Battery Materials Research (BMR) Program, under Contract No. DE-SC0012704. This research used resources of 3-ID (HXN), 7-BM (QAS), and 8-ID(ISS) of the National Synchrotron Light Source II, a Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Brookhaven National Laboratory under Contract No. DE-SC0012704. We thank Michael Wojcik at the Argonne National Laboratory (USA) for providing the X-ray zoneplate used for this work.

Funding Information:
The work doen at KIST was supported by Nano-Material Technology Program (NRF- 2020M3H4A3081889 ) of the National Research Foundation (NRF) funded by the Ministry of Science & ICT and KIST Institutional Program (No. 2E31860). Xiao-Qing Yang at the Brookhaven National Lab was supported by the U.S. Department of Energy, the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies, through the Advanced Battery Materials Research (BMR) Program, under Contract No. DE-SC0012704. This research used resources of 3-ID (HXN), 7-BM (QAS), and 8-ID(ISS) of the National Synchrotron Light Source II, a Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Brookhaven National Laboratory under Contract No. DE-SC0012704. We thank Michael Wojcik at the Argonne National Laboratory (USA) for providing the X-ray zoneplate used for this work.

Publisher Copyright:
© 2022 The Author(s)

All Science Journal Classification (ASJC) codes

Chemistry(all)
Environmental Chemistry
Chemical Engineering(all)
Industrial and Manufacturing Engineering

Access to Document

10.1016/j.cej.2022.135791

Cite this

Ali, G., Islam, M., Bhange, D. S., Jung, Y. H., Ge, M., Chu, Y. S., Nam, K. W., Du, Y., Yang, X. Q., Jung, H. G., Bak, S. M., & Chung, K. Y. (2022). Self-standing Co_2.4Sn_0.6O₄ nano rods as high performance anode materials for sodium-ion battery and investigation on its reaction mechanism. Chemical Engineering Journal, 439, [135791]. https://doi.org/10.1016/j.cej.2022.135791

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title = "Self-standing Co2.4Sn0.6O4 nano rods as high performance anode materials for sodium-ion battery and investigation on its reaction mechanism",

abstract = "The self-standing nanorod Co2.4Sn0.6O4 is synthesized as a high-performance anode material in search of high capacity and stable anode materials for sodium-ion batteries. The Co2.4Sn0.6O4 nanorod exhibits a high reversible capacity of 576 mAh g−1 at a current density of 80 mA g−1 and shows excellent high-rate capability. The X-ray absorption spectroscopy study reveals the mechanisms of charge storage reaction and improved cycling performance of Co2.4Sn0.6O4. A partially limited conversion reaction of Co– and Sn-oxide during the cycling effectively regulate the irreversible capacity loss over the cycling that is commonly observed from the conversion and alloying reaction-based anode materials. Furthermore, Co2.4Sn0.6O4 also exhibits superior sodium-ion full cell performance when coupled with a NaNi2/3Bi1/3O2 cathode, demonstrating an energy density of 262 Wh kg−1.",

author = "Ghulam Ali and Mobinul Islam and Bhange, {Deu S.} and Jung, {Young Hwa} and Mingyuan Ge and Chu, {Yong S.} and Nam, {Kyung Wan} and Yonghua Du and Yang, {Xiao Qing} and Jung, {Hun Gi} and Bak, {Seong Min} and Chung, {Kyung Yoon}",

note = "Funding Information: The work doen at KIST was supported by Nano-Material Technology Program (NRF-2020M3H4A3081889) of the National Research Foundation (NRF) funded by the Ministry of Science & ICT and KIST Institutional Program (No. 2E31860). Xiao-Qing Yang at the Brookhaven National Lab was supported by the U.S. Department of Energy, the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies, through the Advanced Battery Materials Research (BMR) Program, under Contract No. DE-SC0012704. This research used resources of 3-ID (HXN), 7-BM (QAS), and 8-ID(ISS) of the National Synchrotron Light Source II, a Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Brookhaven National Laboratory under Contract No. DE-SC0012704. We thank Michael Wojcik at the Argonne National Laboratory (USA) for providing the X-ray zoneplate used for this work. Funding Information: The work doen at KIST was supported by Nano-Material Technology Program (NRF- 2020M3H4A3081889 ) of the National Research Foundation (NRF) funded by the Ministry of Science & ICT and KIST Institutional Program (No. 2E31860). Xiao-Qing Yang at the Brookhaven National Lab was supported by the U.S. Department of Energy, the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies, through the Advanced Battery Materials Research (BMR) Program, under Contract No. DE-SC0012704. This research used resources of 3-ID (HXN), 7-BM (QAS), and 8-ID(ISS) of the National Synchrotron Light Source II, a Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Brookhaven National Laboratory under Contract No. DE-SC0012704. We thank Michael Wojcik at the Argonne National Laboratory (USA) for providing the X-ray zoneplate used for this work. Publisher Copyright: {\textcopyright} 2022 The Author(s)",

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doi = "10.1016/j.cej.2022.135791",

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T1 - Self-standing Co2.4Sn0.6O4 nano rods as high performance anode materials for sodium-ion battery and investigation on its reaction mechanism

AU - Ali, Ghulam

AU - Islam, Mobinul

AU - Bhange, Deu S.

AU - Jung, Young Hwa

AU - Ge, Mingyuan

AU - Chu, Yong S.

AU - Nam, Kyung Wan

AU - Du, Yonghua

AU - Yang, Xiao Qing

AU - Jung, Hun Gi

AU - Bak, Seong Min

AU - Chung, Kyung Yoon

N1 - Funding Information: The work doen at KIST was supported by Nano-Material Technology Program (NRF-2020M3H4A3081889) of the National Research Foundation (NRF) funded by the Ministry of Science & ICT and KIST Institutional Program (No. 2E31860). Xiao-Qing Yang at the Brookhaven National Lab was supported by the U.S. Department of Energy, the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies, through the Advanced Battery Materials Research (BMR) Program, under Contract No. DE-SC0012704. This research used resources of 3-ID (HXN), 7-BM (QAS), and 8-ID(ISS) of the National Synchrotron Light Source II, a Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Brookhaven National Laboratory under Contract No. DE-SC0012704. We thank Michael Wojcik at the Argonne National Laboratory (USA) for providing the X-ray zoneplate used for this work. Funding Information: The work doen at KIST was supported by Nano-Material Technology Program (NRF- 2020M3H4A3081889 ) of the National Research Foundation (NRF) funded by the Ministry of Science & ICT and KIST Institutional Program (No. 2E31860). Xiao-Qing Yang at the Brookhaven National Lab was supported by the U.S. Department of Energy, the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies, through the Advanced Battery Materials Research (BMR) Program, under Contract No. DE-SC0012704. This research used resources of 3-ID (HXN), 7-BM (QAS), and 8-ID(ISS) of the National Synchrotron Light Source II, a Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Brookhaven National Laboratory under Contract No. DE-SC0012704. We thank Michael Wojcik at the Argonne National Laboratory (USA) for providing the X-ray zoneplate used for this work. Publisher Copyright: © 2022 The Author(s)

PY - 2022/7/1

Y1 - 2022/7/1

N2 - The self-standing nanorod Co2.4Sn0.6O4 is synthesized as a high-performance anode material in search of high capacity and stable anode materials for sodium-ion batteries. The Co2.4Sn0.6O4 nanorod exhibits a high reversible capacity of 576 mAh g−1 at a current density of 80 mA g−1 and shows excellent high-rate capability. The X-ray absorption spectroscopy study reveals the mechanisms of charge storage reaction and improved cycling performance of Co2.4Sn0.6O4. A partially limited conversion reaction of Co– and Sn-oxide during the cycling effectively regulate the irreversible capacity loss over the cycling that is commonly observed from the conversion and alloying reaction-based anode materials. Furthermore, Co2.4Sn0.6O4 also exhibits superior sodium-ion full cell performance when coupled with a NaNi2/3Bi1/3O2 cathode, demonstrating an energy density of 262 Wh kg−1.

AB - The self-standing nanorod Co2.4Sn0.6O4 is synthesized as a high-performance anode material in search of high capacity and stable anode materials for sodium-ion batteries. The Co2.4Sn0.6O4 nanorod exhibits a high reversible capacity of 576 mAh g−1 at a current density of 80 mA g−1 and shows excellent high-rate capability. The X-ray absorption spectroscopy study reveals the mechanisms of charge storage reaction and improved cycling performance of Co2.4Sn0.6O4. A partially limited conversion reaction of Co– and Sn-oxide during the cycling effectively regulate the irreversible capacity loss over the cycling that is commonly observed from the conversion and alloying reaction-based anode materials. Furthermore, Co2.4Sn0.6O4 also exhibits superior sodium-ion full cell performance when coupled with a NaNi2/3Bi1/3O2 cathode, demonstrating an energy density of 262 Wh kg−1.

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