Separation of gas mixtures using Co(II) carborane-based porous coordination polymers

Youn-Sang Bae, Alexander M. Spokoyny, Omar K. Farha, Randall Q. Snurr, Joseph T. Hupp, Chad A. Mirkin

Research output: Contribution to journalArticle

106 Citations (Scopus)

Abstract

Separations of CO2/CH4, CO2/N2, and O2/N2 mixtures were studied in three porous coordination polymers made of the same carborane ligand and Co(ii) nodes. High selectivities for CO2 over CH4 (∼47) and CO 2 over N2 (∼95) were obtained, especially in the material with coordinated pyridine. Unusual selectivity for O2 over N2 (as high as 6.5) was demonstrated in the materials with open Co(ii) sites.

Original languageEnglish
Pages (from-to)3478-3480
Number of pages3
JournalChemical Communications
Volume46
Issue number20
DOIs
Publication statusPublished - 2010 May 21

Fingerprint

Gas mixtures
Polymers
Carbon Monoxide
Pyridine
Ligands
pyridine

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Bae, Y-S., Spokoyny, A. M., Farha, O. K., Snurr, R. Q., Hupp, J. T., & Mirkin, C. A. (2010). Separation of gas mixtures using Co(II) carborane-based porous coordination polymers. Chemical Communications, 46(20), 3478-3480. https://doi.org/10.1039/b927499e
Bae, Youn-Sang ; Spokoyny, Alexander M. ; Farha, Omar K. ; Snurr, Randall Q. ; Hupp, Joseph T. ; Mirkin, Chad A. / Separation of gas mixtures using Co(II) carborane-based porous coordination polymers. In: Chemical Communications. 2010 ; Vol. 46, No. 20. pp. 3478-3480.
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Bae, Y-S, Spokoyny, AM, Farha, OK, Snurr, RQ, Hupp, JT & Mirkin, CA 2010, 'Separation of gas mixtures using Co(II) carborane-based porous coordination polymers', Chemical Communications, vol. 46, no. 20, pp. 3478-3480. https://doi.org/10.1039/b927499e

Separation of gas mixtures using Co(II) carborane-based porous coordination polymers. / Bae, Youn-Sang; Spokoyny, Alexander M.; Farha, Omar K.; Snurr, Randall Q.; Hupp, Joseph T.; Mirkin, Chad A.

In: Chemical Communications, Vol. 46, No. 20, 21.05.2010, p. 3478-3480.

Research output: Contribution to journalArticle

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AU - Spokoyny, Alexander M.

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AU - Hupp, Joseph T.

AU - Mirkin, Chad A.

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AB - Separations of CO2/CH4, CO2/N2, and O2/N2 mixtures were studied in three porous coordination polymers made of the same carborane ligand and Co(ii) nodes. High selectivities for CO2 over CH4 (∼47) and CO 2 over N2 (∼95) were obtained, especially in the material with coordinated pyridine. Unusual selectivity for O2 over N2 (as high as 6.5) was demonstrated in the materials with open Co(ii) sites.

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