Shaped platinum nanoparticles directly synthesized inside mesoporous silica supports

Jiwhan Kim, Youn-Sang Bae, Hyunjoo Lee

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

It is difficult to deposit shape-controlled nanoparticles into a mesoporous framework while preserving the shape. For shaped platinum nanoparticles, which are typically 5-10 nm in size, capillary inclusion by sonication or the formation of a mesoporous framework around the shaped platinum nanoparticles has been attempted, but the nanoparticles aggregated or their shapes were degraded easily. In this work, we directly nucleated platinum on the surface inside a mesoporous silica support and controlled the overgrowth step, producing cubic shaped nanoparticles. Mercaptopropyltrimethoxysilane was used as an anchoring agent causing nucleation at the silica surface, and it also helped to shape the nanoparticles. Platinum nanocubes, which were synthesized with polymeric capping agents separately, were deposited inside the mesoporous silica by sonication, but most of the nanoparticles were clogged at the entrance to the pores, and the surface of the platinum had very few sites that were catalytically active, as evidenced by the small H2 uptake. Unshaped platinum nanoparticles, which were prepared by conventional wet impregnation, showed a similar amount of H2 uptake as the in situ shaped platinum cubes, but the selectivity for pyrrole hydrogenation was poorer towards the production of pyrrolidine. The mesoporosity and the residual thiol groups on the surface of the in situ shaped Pt nanocubes might cause a high selectivity for pyrrolidine.

Original languageEnglish
Pages (from-to)12540-12546
Number of pages7
JournalNanoscale
Volume6
Issue number21
DOIs
Publication statusPublished - 2014 Jan 1

Fingerprint

Platinum
Silicon Dioxide
Silica
Nanoparticles
Sonication
Pyrroles
Sulfhydryl Compounds
Impregnation
Hydrogenation
Nucleation
Deposits

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

Kim, Jiwhan ; Bae, Youn-Sang ; Lee, Hyunjoo. / Shaped platinum nanoparticles directly synthesized inside mesoporous silica supports. In: Nanoscale. 2014 ; Vol. 6, No. 21. pp. 12540-12546.
@article{ea42d797abc04936887da3a83ec71868,
title = "Shaped platinum nanoparticles directly synthesized inside mesoporous silica supports",
abstract = "It is difficult to deposit shape-controlled nanoparticles into a mesoporous framework while preserving the shape. For shaped platinum nanoparticles, which are typically 5-10 nm in size, capillary inclusion by sonication or the formation of a mesoporous framework around the shaped platinum nanoparticles has been attempted, but the nanoparticles aggregated or their shapes were degraded easily. In this work, we directly nucleated platinum on the surface inside a mesoporous silica support and controlled the overgrowth step, producing cubic shaped nanoparticles. Mercaptopropyltrimethoxysilane was used as an anchoring agent causing nucleation at the silica surface, and it also helped to shape the nanoparticles. Platinum nanocubes, which were synthesized with polymeric capping agents separately, were deposited inside the mesoporous silica by sonication, but most of the nanoparticles were clogged at the entrance to the pores, and the surface of the platinum had very few sites that were catalytically active, as evidenced by the small H2 uptake. Unshaped platinum nanoparticles, which were prepared by conventional wet impregnation, showed a similar amount of H2 uptake as the in situ shaped platinum cubes, but the selectivity for pyrrole hydrogenation was poorer towards the production of pyrrolidine. The mesoporosity and the residual thiol groups on the surface of the in situ shaped Pt nanocubes might cause a high selectivity for pyrrolidine.",
author = "Jiwhan Kim and Youn-Sang Bae and Hyunjoo Lee",
year = "2014",
month = "1",
day = "1",
doi = "10.1039/c4nr03951c",
language = "English",
volume = "6",
pages = "12540--12546",
journal = "Nanoscale",
issn = "2040-3364",
publisher = "Royal Society of Chemistry",
number = "21",

}

Shaped platinum nanoparticles directly synthesized inside mesoporous silica supports. / Kim, Jiwhan; Bae, Youn-Sang; Lee, Hyunjoo.

In: Nanoscale, Vol. 6, No. 21, 01.01.2014, p. 12540-12546.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Shaped platinum nanoparticles directly synthesized inside mesoporous silica supports

AU - Kim, Jiwhan

AU - Bae, Youn-Sang

AU - Lee, Hyunjoo

PY - 2014/1/1

Y1 - 2014/1/1

N2 - It is difficult to deposit shape-controlled nanoparticles into a mesoporous framework while preserving the shape. For shaped platinum nanoparticles, which are typically 5-10 nm in size, capillary inclusion by sonication or the formation of a mesoporous framework around the shaped platinum nanoparticles has been attempted, but the nanoparticles aggregated or their shapes were degraded easily. In this work, we directly nucleated platinum on the surface inside a mesoporous silica support and controlled the overgrowth step, producing cubic shaped nanoparticles. Mercaptopropyltrimethoxysilane was used as an anchoring agent causing nucleation at the silica surface, and it also helped to shape the nanoparticles. Platinum nanocubes, which were synthesized with polymeric capping agents separately, were deposited inside the mesoporous silica by sonication, but most of the nanoparticles were clogged at the entrance to the pores, and the surface of the platinum had very few sites that were catalytically active, as evidenced by the small H2 uptake. Unshaped platinum nanoparticles, which were prepared by conventional wet impregnation, showed a similar amount of H2 uptake as the in situ shaped platinum cubes, but the selectivity for pyrrole hydrogenation was poorer towards the production of pyrrolidine. The mesoporosity and the residual thiol groups on the surface of the in situ shaped Pt nanocubes might cause a high selectivity for pyrrolidine.

AB - It is difficult to deposit shape-controlled nanoparticles into a mesoporous framework while preserving the shape. For shaped platinum nanoparticles, which are typically 5-10 nm in size, capillary inclusion by sonication or the formation of a mesoporous framework around the shaped platinum nanoparticles has been attempted, but the nanoparticles aggregated or their shapes were degraded easily. In this work, we directly nucleated platinum on the surface inside a mesoporous silica support and controlled the overgrowth step, producing cubic shaped nanoparticles. Mercaptopropyltrimethoxysilane was used as an anchoring agent causing nucleation at the silica surface, and it also helped to shape the nanoparticles. Platinum nanocubes, which were synthesized with polymeric capping agents separately, were deposited inside the mesoporous silica by sonication, but most of the nanoparticles were clogged at the entrance to the pores, and the surface of the platinum had very few sites that were catalytically active, as evidenced by the small H2 uptake. Unshaped platinum nanoparticles, which were prepared by conventional wet impregnation, showed a similar amount of H2 uptake as the in situ shaped platinum cubes, but the selectivity for pyrrole hydrogenation was poorer towards the production of pyrrolidine. The mesoporosity and the residual thiol groups on the surface of the in situ shaped Pt nanocubes might cause a high selectivity for pyrrolidine.

UR - http://www.scopus.com/inward/record.url?scp=84908010482&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84908010482&partnerID=8YFLogxK

U2 - 10.1039/c4nr03951c

DO - 10.1039/c4nr03951c

M3 - Article

VL - 6

SP - 12540

EP - 12546

JO - Nanoscale

JF - Nanoscale

SN - 2040-3364

IS - 21

ER -