Simple and effective fabrication of Sb2Te3 films embedded with Ag2Te nanoprecipitates for enhanced thermoelectric performance

Jiwon Kim, Kyu Hyoung Lee, Sung Dae Kim, Jae Hong Lim, Nosang V. Myung

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The embedding of nanoprecipitates into a semiconducting matrix can lead to improved thermoelectric performances by enhancing the power factor or reducing the thermal conductivity of the system in which they are incorporated. Thus, we herein demonstrate the successive annealing of an electrodeposited amorphous Ag-Sb-Te film for the simple and effective fabrication of a nanocomposite consisting of highly dense (∼6 vol%) β-Ag2Te nanoprecipitates in an Ag-doped Sb2Te3 matrix. During the annealing process, nanoscale (∼40 nm) β-Ag2Te precipitates were generated spontaneously due to differences in the binding energies of the Ag-Te and Sb-Te bonds. As a result, the electron-transport properties of the p-type Sb2Te3 were significantly enhanced in the presence of the β-Ag2Te nanoprecipitates owing to an energy-dependent carrier-filtering effect at the Ag-doped Sb2Te3/β-Ag2Te interface. Furthermore, a high power factor of 1870 μW m-1 K-2 was obtained at 300 K due to the increased density of states effective mass (m∗ ∼1.8m0) without any significant deterioration in the electrical conductivity being observed.

Original languageEnglish
Pages (from-to)349-356
Number of pages8
JournalJournal of Materials Chemistry A
Volume6
Issue number2
DOIs
Publication statusPublished - 2018 Jan 1

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Annealing
Electron transport properties
Fabrication
Binding energy
Deterioration
Precipitates
Thermal conductivity
Nanocomposites
Electric Conductivity

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

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title = "Simple and effective fabrication of Sb2Te3 films embedded with Ag2Te nanoprecipitates for enhanced thermoelectric performance",
abstract = "The embedding of nanoprecipitates into a semiconducting matrix can lead to improved thermoelectric performances by enhancing the power factor or reducing the thermal conductivity of the system in which they are incorporated. Thus, we herein demonstrate the successive annealing of an electrodeposited amorphous Ag-Sb-Te film for the simple and effective fabrication of a nanocomposite consisting of highly dense (∼6 vol{\%}) β-Ag2Te nanoprecipitates in an Ag-doped Sb2Te3 matrix. During the annealing process, nanoscale (∼40 nm) β-Ag2Te precipitates were generated spontaneously due to differences in the binding energies of the Ag-Te and Sb-Te bonds. As a result, the electron-transport properties of the p-type Sb2Te3 were significantly enhanced in the presence of the β-Ag2Te nanoprecipitates owing to an energy-dependent carrier-filtering effect at the Ag-doped Sb2Te3/β-Ag2Te interface. Furthermore, a high power factor of 1870 μW m-1 K-2 was obtained at 300 K due to the increased density of states effective mass (m∗ ∼1.8m0) without any significant deterioration in the electrical conductivity being observed.",
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Simple and effective fabrication of Sb2Te3 films embedded with Ag2Te nanoprecipitates for enhanced thermoelectric performance. / Kim, Jiwon; Lee, Kyu Hyoung; Kim, Sung Dae; Lim, Jae Hong; Myung, Nosang V.

In: Journal of Materials Chemistry A, Vol. 6, No. 2, 01.01.2018, p. 349-356.

Research output: Contribution to journalArticle

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