Abstract
A method for simultaneous determination of 12 priority phthalates, adipate and polycyclic aromatic hydrocarbons (PAHs) in edible oils by isotope dilution-gas chromatography-mass spectrometry (ID-GC-MS) was developed for fast, accurate and trace analysis. The extraction and clean-up procedures were optimised, and using stable isotope-labelled internal standards for each analyte, relative standard deviations (RSDs) of 0.92-10.6% and spiked sample recoveries of 80.6-97.8% were obtained. Limits of detection for PAHs were in the range of 0.15-0.77 μg/kg and those for phthalates were in the range of 4.6-10.0 μg/kg. The calibration curves exhibited good linearities with regression coefficients of R2 ≥ 0.99. Twelve edible oils were examined to evaluate the efficiency of this method. Among the 12 analytes, dibutyl phthalates (DBP), diethylhexyl phthalates (DEHP), diethylhexyl adipate (DEHA), benzo[a]anthracene (B[a]A), chrysene (Chry) and benzo[b]fluoranthene (B[b]F) were detected in the range of 1.17-806 μg/kg.
| Original language | English |
|---|---|
| Pages (from-to) | 168-175 |
| Number of pages | 8 |
| Journal | Food Additives and Contaminants: Part B Surveillance |
| Volume | 7 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - 2014 Jan 1 |
Fingerprint
All Science Journal Classification (ASJC) codes
- Food Science
- Toxicology
- Public Health, Environmental and Occupational Health
Cite this
}
Simultaneous analysis of phthalates, adipate and polycyclic aromatic hydrocarbons in edible oils using isotope dilution-gas chromatography-mass spectrometry. / Oh, Min Seok; Lee, Seon Hwa; Moon, Myeong Hee; Lee, Dong Soo; Park, Hyun Mee.
In: Food Additives and Contaminants: Part B Surveillance, Vol. 7, No. 3, 01.01.2014, p. 168-175.Research output: Contribution to journal › Article
TY - JOUR
T1 - Simultaneous analysis of phthalates, adipate and polycyclic aromatic hydrocarbons in edible oils using isotope dilution-gas chromatography-mass spectrometry
AU - Oh, Min Seok
AU - Lee, Seon Hwa
AU - Moon, Myeong Hee
AU - Lee, Dong Soo
AU - Park, Hyun Mee
PY - 2014/1/1
Y1 - 2014/1/1
N2 - A method for simultaneous determination of 12 priority phthalates, adipate and polycyclic aromatic hydrocarbons (PAHs) in edible oils by isotope dilution-gas chromatography-mass spectrometry (ID-GC-MS) was developed for fast, accurate and trace analysis. The extraction and clean-up procedures were optimised, and using stable isotope-labelled internal standards for each analyte, relative standard deviations (RSDs) of 0.92-10.6% and spiked sample recoveries of 80.6-97.8% were obtained. Limits of detection for PAHs were in the range of 0.15-0.77 μg/kg and those for phthalates were in the range of 4.6-10.0 μg/kg. The calibration curves exhibited good linearities with regression coefficients of R2 ≥ 0.99. Twelve edible oils were examined to evaluate the efficiency of this method. Among the 12 analytes, dibutyl phthalates (DBP), diethylhexyl phthalates (DEHP), diethylhexyl adipate (DEHA), benzo[a]anthracene (B[a]A), chrysene (Chry) and benzo[b]fluoranthene (B[b]F) were detected in the range of 1.17-806 μg/kg.
AB - A method for simultaneous determination of 12 priority phthalates, adipate and polycyclic aromatic hydrocarbons (PAHs) in edible oils by isotope dilution-gas chromatography-mass spectrometry (ID-GC-MS) was developed for fast, accurate and trace analysis. The extraction and clean-up procedures were optimised, and using stable isotope-labelled internal standards for each analyte, relative standard deviations (RSDs) of 0.92-10.6% and spiked sample recoveries of 80.6-97.8% were obtained. Limits of detection for PAHs were in the range of 0.15-0.77 μg/kg and those for phthalates were in the range of 4.6-10.0 μg/kg. The calibration curves exhibited good linearities with regression coefficients of R2 ≥ 0.99. Twelve edible oils were examined to evaluate the efficiency of this method. Among the 12 analytes, dibutyl phthalates (DBP), diethylhexyl phthalates (DEHP), diethylhexyl adipate (DEHA), benzo[a]anthracene (B[a]A), chrysene (Chry) and benzo[b]fluoranthene (B[b]F) were detected in the range of 1.17-806 μg/kg.
UR - http://www.scopus.com/inward/record.url?scp=84904510426&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84904510426&partnerID=8YFLogxK
U2 - 10.1080/19393210.2013.869770
DO - 10.1080/19393210.2013.869770
M3 - Article
VL - 7
SP - 168
EP - 175
JO - Food Additives and Contaminants: Part B Surveillance
JF - Food Additives and Contaminants: Part B Surveillance
SN - 1939-3210
IS - 3
ER -