Simultaneous modification of pyrolysis and densification for low-temperature solution-processed flexible oxide thin-film transistors

You Seung Rim, Woong Hee Jeong, Dong Lim Kim, Hyun Soo Lim, Kyung Min Kim, Hyun Jae Kim

Research output: Contribution to journalArticle

129 Citations (Scopus)

Abstract

High-pressure annealing (HPA) affected the thermodynamics of the formation of a solution-processed oxide film through the simultaneous modification of thermal decomposition and compression, and enabled the use of lower annealing temperatures, which was favourable for device implementation. HPA also reduced the film thickness and decreased the porosity, resulting in enhanced device characteristics at low temperature. Surface and depth profile characterization using X-ray reflectivity (XRR), X-ray photoelectron spectroscopy (XPS), time-of-flight secondary ion mass spectrometry (TOF-SIMS), and ellipsometry suggested that the HPA process supported the effective decomposition of commercial metal-nitrate and/or -salt precursors and strong bonding between oxygen and the metal ions, ultimately reducing the amount of organic residue. The as-optimized HPA process allowed for high-performance solution-processed flexible InZnO (IZO) TFTs on a polymeric substrate at 220 °C with low sub-threshold voltage swing (as low as 0.56 V dec-1), high on-off ratio of over 106, and field-effect mobility as high as 1.78 cm 2 V-1 s-1, respectively. These results demonstrate that this is a simple and efficient promising approach for improving the performance of solution-processed electronic devices at low temperatures.

Original languageEnglish
Pages (from-to)12491-12497
Number of pages7
JournalJournal of Materials Chemistry
Volume22
Issue number25
DOIs
Publication statusPublished - 2012 Jul 7

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Thin film transistors
Densification
Oxide films
Pyrolysis
Annealing
Temperature
Ellipsometry
Secondary ion mass spectrometry
Threshold voltage
Nitrates
Metal ions
Film thickness
X ray photoelectron spectroscopy
Salts
Porosity
Metals
Thermodynamics
Oxygen
Decomposition
X rays

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Chemistry

Cite this

Rim, You Seung ; Jeong, Woong Hee ; Kim, Dong Lim ; Lim, Hyun Soo ; Kim, Kyung Min ; Kim, Hyun Jae. / Simultaneous modification of pyrolysis and densification for low-temperature solution-processed flexible oxide thin-film transistors. In: Journal of Materials Chemistry. 2012 ; Vol. 22, No. 25. pp. 12491-12497.
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Simultaneous modification of pyrolysis and densification for low-temperature solution-processed flexible oxide thin-film transistors. / Rim, You Seung; Jeong, Woong Hee; Kim, Dong Lim; Lim, Hyun Soo; Kim, Kyung Min; Kim, Hyun Jae.

In: Journal of Materials Chemistry, Vol. 22, No. 25, 07.07.2012, p. 12491-12497.

Research output: Contribution to journalArticle

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AU - Kim, Hyun Jae

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