Soft X-ray spectroscopic study of dense strontium-doped lanthanum manganite cathodes for solid oxide fuel cell applications

L. F.J. Piper, A. R.H. Preston, S. W. Cho, A. Demasi, B. Chen, J. Laverock, K. E. Smith, L. J. Miara, J. N. Davis, S. N. Basu, U. Pal, S. Gopalan, Laxmikant Saraf, Tiffany Kaspar, A. Y. Matsuura, P. A. Glans, J. H. Guo

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Abstract

The evolution of the Mn charge state, chemical composition, and electronic structure of La0.8 Sr0.2 Mn O3 (LSMO) cathodes during the catalytic activation of solid oxide fuel cell (SOFC) has been studies using X-ray spectroscopy of as-processed, exposed, and activated dense thin LSMO films. Comparison of O K-edge and Mn L3,2-edge X-ray absorption spectra from the different stages of LSMO cathodes revealed that the largest change after the activation occurred in the Mn charge state with little change in the oxygen environment. Core-level X-ray photoemission spectroscopy and Mn L 3 resonant photoemission spectroscopy studies of exposed and as-processed LSMO determined that the SOFC environment (800°C ambient pressure of O2) alone results in La deficiency (severest near the surface with Sr doping >0.55) and a stronger Mn4+ contribution, leading to the increased insulating character of the cathode prior to activation. Meanwhile, O K-edge X-ray absorption measurements support Sr/La enrichment nearer the surface, along with the formation of mixed Srx Mny Oz and/or passive Mn Ox and SrO species.

Original languageEnglish
Pages (from-to)B99-B105
JournalJournal of the Electrochemical Society
Volume158
Issue number2
DOIs
Publication statusPublished - 2011 Jan 5

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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    Piper, L. F. J., Preston, A. R. H., Cho, S. W., Demasi, A., Chen, B., Laverock, J., Smith, K. E., Miara, L. J., Davis, J. N., Basu, S. N., Pal, U., Gopalan, S., Saraf, L., Kaspar, T., Matsuura, A. Y., Glans, P. A., & Guo, J. H. (2011). Soft X-ray spectroscopic study of dense strontium-doped lanthanum manganite cathodes for solid oxide fuel cell applications. Journal of the Electrochemical Society, 158(2), B99-B105. https://doi.org/10.1149/1.3519075