Solar-to-hydrogen peroxide conversion of photocatalytic carbon dots with anthraquinone: Unveiling the dual role of surface functionalities

Minsu Gu, Do Yeon Lee, Jinhong Mun, Dongseok Kim, Hae in Cho, Bupmo Kim, Wooyul Kim, Geunsik Lee, Byeong Su Kim, Hyoung il Kim

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Solar-driven photocatalytic production of hydrogen peroxide (H2O2) requires only sunlight, oxygen, and water, making it a green and sustainable alternative to conventional H2O2 production processes. We present photocatalytic carbon dots (CDs) as a new candidate for high-performance H2O2 production. Owing to the generation of an excellent charge carrier and the presence of various oxygen-containing functional groups, CDs showed an outstanding H2O2 production capability of 609.4 μmol g−1 h−1 even in the absence of an electron donor, demonstrating promising self-electron-donating capabilities. Hydroxyl groups on their surface, in particular, serve a dual role as photocatalytic active sites and as electron and proton donors toward the oxygen reduction reaction (ORR). The photocatalytic activity of CDs was significantly improved to 1187.8 μmol g−1 by functionalizing their surfaces with anthraquinone (AQ) as a co-catalyst; it promoted the charge carrier separation and electrochemically favored the two-electron pathway of ORR. These carbon-based metal-free nanohybrids that are a unique combination of CDs and AQ could offer insights into designing efficient photocatalysts for future solar-to-H2O2 conversion systems.

Original languageEnglish
Article number121379
JournalApplied Catalysis B: Environmental
Volume312
DOIs
Publication statusPublished - 2022 Sep 5

Bibliographical note

Funding Information:
We thank Mr. Taehyung Kim and Ms. Namhee Kim for assisting with the acquisition of solid-state 13 C NMR spectra. This work was supported by the National Research Foundation of Republic of Korea ( NRF-2021R1F1A1063702 , NRF-2021R1C1C1007706 , NRF-2021M3H4A1A03049662 , NRF-2017R1A2B3012148 , and NRF-2017M3A7B4052802 ) and by ICONS (Institute of Convergence Science), Yonsei University .

Publisher Copyright:
© 2022 Elsevier B.V.

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Environmental Science(all)
  • Process Chemistry and Technology

Fingerprint

Dive into the research topics of 'Solar-to-hydrogen peroxide conversion of photocatalytic carbon dots with anthraquinone: Unveiling the dual role of surface functionalities'. Together they form a unique fingerprint.

Cite this