Solid state organic amine detection in a photochromic porous metal organic framework

Arijit Mallick, Bikash Garai, Matthew A. Addicoat, Petko St Petkov, Thomas Heine, Rahul Banerjee

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198 Citations (Scopus)

Abstract

A new Mg(ii) based photochromic porous metal-organic framework (MOF) has been synthesized bearing naphthalenediimide (NDI) chromophoric unit. This MOF (Mg-NDI) shows instant and reversible solvatochromic behavior in presence of solvents with different polarity. Mg-NDI also exhibits fast and reversible photochromism via radical formation. Due to the presence of electron deficient NDI moiety, this MOF exhibits selective organic amine (electron rich) sensing in solid state. The organic amine detection has been confirmed by photoluminescence quenching experiment and visual color change.

Original languageEnglish
Pages (from-to)1420-1425
Number of pages6
JournalChemical Science
Volume6
Issue number2
DOIs
Publication statusPublished - 2015 Feb 1

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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    Mallick, A., Garai, B., Addicoat, M. A., Petkov, P. S., Heine, T., & Banerjee, R. (2015). Solid state organic amine detection in a photochromic porous metal organic framework. Chemical Science, 6(2), 1420-1425. https://doi.org/10.1039/c4sc03224a