Solvent-free chelation-assisted catalytic C-C bond cleavage of unstrained ketone by rhodium(I) complexes under microwave irradiation

Jeong Ae Ahn, Duck Ho Chang, Jun Park Young, Rim Yon Ye, André Loupy, Chul Ho Jun

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

A highly efficient C-C bond cleavage of unstrained aliphatic ketones bearing β-hydrogens with olefins was achieved using a chelation-assisted catalytic system consisting of (Ph3P)3RhCl and 2-amino-3-picoline by microwave irradiation under solvent-free conditions. The addition of cyclohexylamine catalyst accelerated the reaction rate dramatically under microwave irradiation compared with the classical heating method.

Original languageEnglish
Pages (from-to)55-58
Number of pages4
JournalAdvanced Synthesis and Catalysis
Volume348
Issue number1-2
DOIs
Publication statusPublished - 2006 Jan 1

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Rhodium
Microwave irradiation
Chelation
Ketones
Bearings (structural)
Picolines
Cyclohexylamines
Alkenes
Olefins
Reaction rates
Hydrogen
Heating
Catalysts

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

Cite this

Ahn, Jeong Ae ; Chang, Duck Ho ; Young, Jun Park ; Ye, Rim Yon ; Loupy, André ; Jun, Chul Ho. / Solvent-free chelation-assisted catalytic C-C bond cleavage of unstrained ketone by rhodium(I) complexes under microwave irradiation. In: Advanced Synthesis and Catalysis. 2006 ; Vol. 348, No. 1-2. pp. 55-58.
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Solvent-free chelation-assisted catalytic C-C bond cleavage of unstrained ketone by rhodium(I) complexes under microwave irradiation. / Ahn, Jeong Ae; Chang, Duck Ho; Young, Jun Park; Ye, Rim Yon; Loupy, André; Jun, Chul Ho.

In: Advanced Synthesis and Catalysis, Vol. 348, No. 1-2, 01.01.2006, p. 55-58.

Research output: Contribution to journalArticle

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