Solvent-free chelation-assisted intermolecular hydroacylation: Effect of microwave irradiation in the synthesis of ketone from aldehyde and 1-alkene by Rh(I) complex

Chul Ho Jun; Jong Hwa Chung; Dae Yon Lee; André Loupy; Saber Chatti

doi:10.1016/S0040-4039(01)00853-X

Solvent-free chelation-assisted intermolecular hydroacylation: Effect of microwave irradiation in the synthesis of ketone from aldehyde and 1-alkene by Rh(I) complex

Chul Ho Jun, Jong Hwa Chung, Dae Yon Lee, André Loupy, Saber Chatti

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

As a green alternative to classical homogeneous catalyst in toluene in closed vessels, the intermolecular hydroacylation of 1-alkenes with aldehydes by Rh(I) complex (Wilkinson catalyst) can be realized efficiently under solvent-free conditions. When coupled to microwave activation, it results in a serious improvement when compared to classical conditions.

Original language	English
Pages (from-to)	4803-4805
Number of pages	3
Journal	Tetrahedron Letters
Volume	42
Issue number	29
DOIs	https://doi.org/10.1016/S0040-4039(01)00853-X
Publication status	Published - 2001 Jul 16

Bibliographical note

Funding Information:
This work was supported by the National Research Laboratory (2000-N-NL-01-C-271) Program administrated by the Ministry of Science and Technology, and Brain Korea 21 project.

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(01)00853-X

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abstract = "As a green alternative to classical homogeneous catalyst in toluene in closed vessels, the intermolecular hydroacylation of 1-alkenes with aldehydes by Rh(I) complex (Wilkinson catalyst) can be realized efficiently under solvent-free conditions. When coupled to microwave activation, it results in a serious improvement when compared to classical conditions.",

author = "Jun, {Chul Ho} and Chung, {Jong Hwa} and Lee, {Dae Yon} and Andr{\'e} Loupy and Saber Chatti",

note = "Funding Information: This work was supported by the National Research Laboratory (2000-N-NL-01-C-271) Program administrated by the Ministry of Science and Technology, and Brain Korea 21 project.",

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doi = "10.1016/S0040-4039(01)00853-X",

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T2 - Effect of microwave irradiation in the synthesis of ketone from aldehyde and 1-alkene by Rh(I) complex

AU - Jun, Chul Ho

AU - Chung, Jong Hwa

AU - Lee, Dae Yon

AU - Loupy, André

AU - Chatti, Saber

N1 - Funding Information: This work was supported by the National Research Laboratory (2000-N-NL-01-C-271) Program administrated by the Ministry of Science and Technology, and Brain Korea 21 project.

PY - 2001/7/16

Y1 - 2001/7/16

N2 - As a green alternative to classical homogeneous catalyst in toluene in closed vessels, the intermolecular hydroacylation of 1-alkenes with aldehydes by Rh(I) complex (Wilkinson catalyst) can be realized efficiently under solvent-free conditions. When coupled to microwave activation, it results in a serious improvement when compared to classical conditions.

AB - As a green alternative to classical homogeneous catalyst in toluene in closed vessels, the intermolecular hydroacylation of 1-alkenes with aldehydes by Rh(I) complex (Wilkinson catalyst) can be realized efficiently under solvent-free conditions. When coupled to microwave activation, it results in a serious improvement when compared to classical conditions.

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Solvent-free chelation-assisted intermolecular hydroacylation: Effect of microwave irradiation in the synthesis of ketone from aldehyde and 1-alkene by Rh(I) complex

Abstract

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