Solvent-free microwave-assisted ortho-alkylation of aromatic ketimine with acrylic acid derivatives by Rh(I) catalyst

Eun Ae Jo, Jeong Ae Ahn, Chul-Ho Jun

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Microwave(MW)-assisted ortho-alkylation of aromatic imine with acrylic acid derivatives was performed in the presence of a (PPh3) 3RhCl catalyst, and corresponding ortho-alkylated ketones were obtained after hydrolysis of the resulting ketimines. This solventless MW-assisted ortho-alkylation was highly efficient compared with conventional heating, probably due to the specific MW effect.

Original languageEnglish
Pages (from-to)2020-2024
Number of pages5
JournalBulletin of the Korean Chemical Society
Volume28
Issue number11
DOIs
Publication statusPublished - 2007 Nov 20

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Alkylation
Microwaves
Derivatives
Catalysts
Imines
Ketones
Hydrolysis
Heating
acrylic acid
ketimine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

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Solvent-free microwave-assisted ortho-alkylation of aromatic ketimine with acrylic acid derivatives by Rh(I) catalyst. / Jo, Eun Ae; Ahn, Jeong Ae; Jun, Chul-Ho.

In: Bulletin of the Korean Chemical Society, Vol. 28, No. 11, 20.11.2007, p. 2020-2024.

Research output: Contribution to journalArticle

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