Solvent-free microwave-assisted ortho-alkylation of aromatic ketimine with acrylic acid derivatives by Rh(I) catalyst

Eun Ae Jo, Jeong Ae Ahn, Chul Ho Jun

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Abstract

Microwave(MW)-assisted ortho-alkylation of aromatic imine with acrylic acid derivatives was performed in the presence of a (PPh3) 3RhCl catalyst, and corresponding ortho-alkylated ketones were obtained after hydrolysis of the resulting ketimines. This solventless MW-assisted ortho-alkylation was highly efficient compared with conventional heating, probably due to the specific MW effect.

Original languageEnglish
Pages (from-to)2020-2024
Number of pages5
JournalBulletin of the Korean Chemical Society
Volume28
Issue number11
DOIs
Publication statusPublished - 2007 Nov 20

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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