Solvent-free microwave-assisted ortho-alkylation of aromatic ketimine with acrylic acid derivatives by Rh(I) catalyst

Eun Ae Jo; Jeong Ae Ahn; Chul Ho Jun

doi:10.5012/bkcs.2007.28.11.2020

Solvent-free microwave-assisted ortho-alkylation of aromatic ketimine with acrylic acid derivatives by Rh(I) catalyst

Eun Ae Jo, Jeong Ae Ahn, Chul Ho Jun

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Microwave(MW)-assisted ortho-alkylation of aromatic imine with acrylic acid derivatives was performed in the presence of a (PPh₃) ₃RhCl catalyst, and corresponding ortho-alkylated ketones were obtained after hydrolysis of the resulting ketimines. This solventless MW-assisted ortho-alkylation was highly efficient compared with conventional heating, probably due to the specific MW effect.

Original language	English
Pages (from-to)	2020-2024
Number of pages	5
Journal	Bulletin of the Korean Chemical Society
Volume	28
Issue number	11
DOIs	https://doi.org/10.5012/bkcs.2007.28.11.2020
Publication status	Published - 2007 Nov 20

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.5012/bkcs.2007.28.11.2020

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abstract = "Microwave(MW)-assisted ortho-alkylation of aromatic imine with acrylic acid derivatives was performed in the presence of a (PPh3) 3RhCl catalyst, and corresponding ortho-alkylated ketones were obtained after hydrolysis of the resulting ketimines. This solventless MW-assisted ortho-alkylation was highly efficient compared with conventional heating, probably due to the specific MW effect.",

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AU - Ahn, Jeong Ae

AU - Jun, Chul Ho

PY - 2007/11/20

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N2 - Microwave(MW)-assisted ortho-alkylation of aromatic imine with acrylic acid derivatives was performed in the presence of a (PPh3) 3RhCl catalyst, and corresponding ortho-alkylated ketones were obtained after hydrolysis of the resulting ketimines. This solventless MW-assisted ortho-alkylation was highly efficient compared with conventional heating, probably due to the specific MW effect.

AB - Microwave(MW)-assisted ortho-alkylation of aromatic imine with acrylic acid derivatives was performed in the presence of a (PPh3) 3RhCl catalyst, and corresponding ortho-alkylated ketones were obtained after hydrolysis of the resulting ketimines. This solventless MW-assisted ortho-alkylation was highly efficient compared with conventional heating, probably due to the specific MW effect.

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JO - Bulletin of the Korean Chemical Society

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ER -

Solvent-free microwave-assisted ortho-alkylation of aromatic ketimine with acrylic acid derivatives by Rh(I) catalyst

Abstract

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