TY - JOUR
T1 - Solvent-induced crystalline-state emission and multichromism of a bent π-surface system composed of dibenzocyclooctatetraene units
AU - Nishiuchi, Tomohiko
AU - Tanaka, Keita
AU - Kuwatani, Yoshiyuki
AU - Sung, Jooyoung
AU - Nishinaga, Tohru
AU - Kim, Dongho
AU - Iyoda, Masahiko
PY - 2013/3/25
Y1 - 2013/3/25
N2 - All bent out of shape: The solvent of crystallization effectively enhances the emission of flexible, bent, π-conjugated molecules in the crystalline state owing to control of the packing of the molecules in the structure. Multichromism such as thermochromism and vapochromism also arises from the solvent-controlled packing. This crystalline-state emission is attributable to the flexibility of cyclooctatetraene units of the bent π-conjugated molecules in the solid state (see figure).
AB - All bent out of shape: The solvent of crystallization effectively enhances the emission of flexible, bent, π-conjugated molecules in the crystalline state owing to control of the packing of the molecules in the structure. Multichromism such as thermochromism and vapochromism also arises from the solvent-controlled packing. This crystalline-state emission is attributable to the flexibility of cyclooctatetraene units of the bent π-conjugated molecules in the solid state (see figure).
UR - http://www.scopus.com/inward/record.url?scp=84875161085&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84875161085&partnerID=8YFLogxK
U2 - 10.1002/chem.201203952
DO - 10.1002/chem.201203952
M3 - Article
C2 - 23460399
AN - SCOPUS:84875161085
SN - 0947-6539
VL - 19
SP - 4110
EP - 4116
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 13
ER -