Spectroscopic evidence of α-methylbenzyl radical in the gas phase

Gi Woo Lee, Hyeon Geun Ahn, Tae Kyu Kim, Sang Kuk Lee

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

We report the observation of the spectroscopic evidence of the α-methylbenzyl radical in a corona excited supersonic expansion using a pinhole-type glass nozzle for the first time. The precursors, toluene, ethylbenzene, and isopropylbenzene, seeded in a large amount of inert carrier gas helium, were electrically discharged to produce benzyl-type radicals as a result of the breaking off of a C-H or a C-C bond from the alkyl chain. The vibronic emission spectra, obtained in the visible region from the precursors, were compared to identify the species generated in the corona discharge of the precursors, from which we found the spectroscopic evidence of the α-methylbenzyl radical.

Original languageEnglish
Pages (from-to)193-196
Number of pages4
JournalChemical Physics Letters
Volume465
Issue number4-6
DOIs
Publication statusPublished - 2008 Nov 13

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Helium
Toluene
Nozzles
Gases
vapor phases
Glass
electric corona
pinholes
coronas
nozzles
toluene
emission spectra
helium
expansion
glass
gases
cumene
ethylbenzene

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Lee, Gi Woo ; Ahn, Hyeon Geun ; Kim, Tae Kyu ; Lee, Sang Kuk. / Spectroscopic evidence of α-methylbenzyl radical in the gas phase. In: Chemical Physics Letters. 2008 ; Vol. 465, No. 4-6. pp. 193-196.
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Spectroscopic evidence of α-methylbenzyl radical in the gas phase. / Lee, Gi Woo; Ahn, Hyeon Geun; Kim, Tae Kyu; Lee, Sang Kuk.

In: Chemical Physics Letters, Vol. 465, No. 4-6, 13.11.2008, p. 193-196.

Research output: Contribution to journalArticle

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