Stannylene or metallastanna(IV)ocane: A matter of formalism

Erica Brendler, Erik Wächtler, Thomas Heine, Lyuben Zhechkov, Thorsten Langer, Rainer Pöttgen, Anthony F. Hill, Jörg Wagler

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

Pushmi-pullyu with palladium: Although created by Ïa donation from SnCl2 to a PdII complex, the Sn-Pd bonds in the compounds depicted exhibit formal Ïa donation in the opposite direction. Computational and spectroscopic data support stannylpalladium (Pd I-SnIII) and palladastanna(IV)ocane (Pd0 SnIV) descriptions over stannylene coordination.

Original languageEnglish
Pages (from-to)4696-4700
Number of pages5
JournalAngewandte Chemie - International Edition
Volume50
Issue number20
DOIs
Publication statusPublished - 2011 May 9

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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    Brendler, E., Wächtler, E., Heine, T., Zhechkov, L., Langer, T., Pöttgen, R., Hill, A. F., & Wagler, J. (2011). Stannylene or metallastanna(IV)ocane: A matter of formalism. Angewandte Chemie - International Edition, 50(20), 4696-4700. https://doi.org/10.1002/anie.201007967