Stereoselective ester enolate alkylation and hydroxylation at C-22 of a steroid side chain

Deukjoon Kim; Gyoon Hee Han; Kwon Kim

doi:10.1016/S0040-4039(00)99524-8

Stereoselective ester enolate alkylation and hydroxylation at C-22 of a steroid side chain

Deukjoon Kim, Gyoon Hee Han, Kwon Kim

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Reactions of steroidal acyclic ester enolate 2 with 4-bromo-2-methyl-2-butene and Davis' oxaziridine reagent proceeded with high diastereoselectivity to afford esters 3a and 3b, respectively.

Original language	English
Pages (from-to)	1579-1580
Number of pages	2
Journal	Tetrahedron Letters
Volume	30
Issue number	12
DOIs	https://doi.org/10.1016/S0040-4039(00)99524-8
Publication status	Published - 1989

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/S0040-4039(00)99524-8

Cite this

@article{4d3639062c7f4756a05b59f647d4bded,

title = "Stereoselective ester enolate alkylation and hydroxylation at C-22 of a steroid side chain",

abstract = "Reactions of steroidal acyclic ester enolate 2 with 4-bromo-2-methyl-2-butene and Davis' oxaziridine reagent proceeded with high diastereoselectivity to afford esters 3a and 3b, respectively.",

author = "Deukjoon Kim and {Hee Han}, Gyoon and Kwon Kim",

year = "1989",

doi = "10.1016/S0040-4039(00)99524-8",

language = "English",

volume = "30",

pages = "1579--1580",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "12",

}

TY - JOUR

T1 - Stereoselective ester enolate alkylation and hydroxylation at C-22 of a steroid side chain

AU - Kim, Deukjoon

AU - Hee Han, Gyoon

AU - Kim, Kwon

PY - 1989

Y1 - 1989

N2 - Reactions of steroidal acyclic ester enolate 2 with 4-bromo-2-methyl-2-butene and Davis' oxaziridine reagent proceeded with high diastereoselectivity to afford esters 3a and 3b, respectively.

AB - Reactions of steroidal acyclic ester enolate 2 with 4-bromo-2-methyl-2-butene and Davis' oxaziridine reagent proceeded with high diastereoselectivity to afford esters 3a and 3b, respectively.

UR - http://www.scopus.com/inward/record.url?scp=0007178581&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0007178581&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)99524-8

DO - 10.1016/S0040-4039(00)99524-8

M3 - Article

AN - SCOPUS:0007178581

SN - 0040-4039

VL - 30

SP - 1579

EP - 1580

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 12

ER -

Stereoselective ester enolate alkylation and hydroxylation at C-22 of a steroid side chain

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this