Stereoselective ester enolate alkylation and hydroxylation at C-22 of a steroid side chain

Deukjoon Kim, Gyoon Hee Han, Kwon Kim

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Reactions of steroidal acyclic ester enolate 2 with 4-bromo-2-methyl-2-butene and Davis' oxaziridine reagent proceeded with high diastereoselectivity to afford esters 3a and 3b, respectively.

Original languageEnglish
Pages (from-to)1579-1580
Number of pages2
JournalTetrahedron Letters
Volume30
Issue number12
DOIs
Publication statusPublished - 1989

Fingerprint

Hydroxylation
Alkylation
Esters
Steroids
2-butene

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

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title = "Stereoselective ester enolate alkylation and hydroxylation at C-22 of a steroid side chain",
abstract = "Reactions of steroidal acyclic ester enolate 2 with 4-bromo-2-methyl-2-butene and Davis' oxaziridine reagent proceeded with high diastereoselectivity to afford esters 3a and 3b, respectively.",
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Stereoselective ester enolate alkylation and hydroxylation at C-22 of a steroid side chain. / Kim, Deukjoon; Hee Han, Gyoon; Kim, Kwon.

In: Tetrahedron Letters, Vol. 30, No. 12, 1989, p. 1579-1580.

Research output: Contribution to journalArticle

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AU - Kim, Deukjoon

AU - Hee Han, Gyoon

AU - Kim, Kwon

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AB - Reactions of steroidal acyclic ester enolate 2 with 4-bromo-2-methyl-2-butene and Davis' oxaziridine reagent proceeded with high diastereoselectivity to afford esters 3a and 3b, respectively.

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