Structural and electrochemical properties of LiAlyCo1-yO2 cathode for Li rechargeable batteries

Won Sub Yoon, Kyung Keun Lee, Kwang Bum Kim

Research output: Contribution to journalArticle

79 Citations (Scopus)

Abstract

LiAlyCo1-yO2 powders were synthesized at 800°C using acrylic acid as a chelating agent. The comparison between local structure refinement of LiCoO2 and LiAl0.25Co0.75O2 during the charging and cycling process was carried out by Co K-edge X-ray absorption spectroscopy (XAS). Al addition was found to cause a larger local structure distortion during Li deintercalation compared to that of LiCoO2. Extended X-ray absorption fine structure refinements during Li deintercalation showed that the degree of structural disorder around Co atoms in LiAl0.25Co0.75O2 becomes higher than that of LiCoO2. XAS analysis for LiCoO2 and LiAl0.25Co0.75O2 during cycling revealed that the large capacity fading of the LiAl0.25Co0.75O2 electrode could be explained by the remaining Co4+ ions and local structure distortion.

Original languageEnglish
Pages (from-to)2023-2028
Number of pages6
JournalJournal of the Electrochemical Society
Volume147
Issue number6
DOIs
Publication statusPublished - 2000 Jun 1

Fingerprint

X ray absorption spectroscopy
Secondary batteries
Electrochemical properties
electric batteries
Structural properties
Cathodes
cathodes
absorption spectroscopy
X ray absorption
Chelating Agents
Chelation
Powders
Acrylics
cycles
x rays
acrylic acid
fading
Ions
Atoms
Electrodes

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Condensed Matter Physics
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

Cite this

@article{d770ae25a6bc4b078ebd501b3e0b119a,
title = "Structural and electrochemical properties of LiAlyCo1-yO2 cathode for Li rechargeable batteries",
abstract = "LiAlyCo1-yO2 powders were synthesized at 800°C using acrylic acid as a chelating agent. The comparison between local structure refinement of LiCoO2 and LiAl0.25Co0.75O2 during the charging and cycling process was carried out by Co K-edge X-ray absorption spectroscopy (XAS). Al addition was found to cause a larger local structure distortion during Li deintercalation compared to that of LiCoO2. Extended X-ray absorption fine structure refinements during Li deintercalation showed that the degree of structural disorder around Co atoms in LiAl0.25Co0.75O2 becomes higher than that of LiCoO2. XAS analysis for LiCoO2 and LiAl0.25Co0.75O2 during cycling revealed that the large capacity fading of the LiAl0.25Co0.75O2 electrode could be explained by the remaining Co4+ ions and local structure distortion.",
author = "Yoon, {Won Sub} and Lee, {Kyung Keun} and Kim, {Kwang Bum}",
year = "2000",
month = "6",
day = "1",
doi = "10.1149/1.1393479",
language = "English",
volume = "147",
pages = "2023--2028",
journal = "Journal of the Electrochemical Society",
issn = "0013-4651",
publisher = "Electrochemical Society, Inc.",
number = "6",

}

Structural and electrochemical properties of LiAlyCo1-yO2 cathode for Li rechargeable batteries. / Yoon, Won Sub; Lee, Kyung Keun; Kim, Kwang Bum.

In: Journal of the Electrochemical Society, Vol. 147, No. 6, 01.06.2000, p. 2023-2028.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Structural and electrochemical properties of LiAlyCo1-yO2 cathode for Li rechargeable batteries

AU - Yoon, Won Sub

AU - Lee, Kyung Keun

AU - Kim, Kwang Bum

PY - 2000/6/1

Y1 - 2000/6/1

N2 - LiAlyCo1-yO2 powders were synthesized at 800°C using acrylic acid as a chelating agent. The comparison between local structure refinement of LiCoO2 and LiAl0.25Co0.75O2 during the charging and cycling process was carried out by Co K-edge X-ray absorption spectroscopy (XAS). Al addition was found to cause a larger local structure distortion during Li deintercalation compared to that of LiCoO2. Extended X-ray absorption fine structure refinements during Li deintercalation showed that the degree of structural disorder around Co atoms in LiAl0.25Co0.75O2 becomes higher than that of LiCoO2. XAS analysis for LiCoO2 and LiAl0.25Co0.75O2 during cycling revealed that the large capacity fading of the LiAl0.25Co0.75O2 electrode could be explained by the remaining Co4+ ions and local structure distortion.

AB - LiAlyCo1-yO2 powders were synthesized at 800°C using acrylic acid as a chelating agent. The comparison between local structure refinement of LiCoO2 and LiAl0.25Co0.75O2 during the charging and cycling process was carried out by Co K-edge X-ray absorption spectroscopy (XAS). Al addition was found to cause a larger local structure distortion during Li deintercalation compared to that of LiCoO2. Extended X-ray absorption fine structure refinements during Li deintercalation showed that the degree of structural disorder around Co atoms in LiAl0.25Co0.75O2 becomes higher than that of LiCoO2. XAS analysis for LiCoO2 and LiAl0.25Co0.75O2 during cycling revealed that the large capacity fading of the LiAl0.25Co0.75O2 electrode could be explained by the remaining Co4+ ions and local structure distortion.

UR - http://www.scopus.com/inward/record.url?scp=0034205716&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034205716&partnerID=8YFLogxK

U2 - 10.1149/1.1393479

DO - 10.1149/1.1393479

M3 - Article

VL - 147

SP - 2023

EP - 2028

JO - Journal of the Electrochemical Society

JF - Journal of the Electrochemical Society

SN - 0013-4651

IS - 6

ER -