Structural confinement effects of ternary chalcogenide in mesoporous ALMCM-41 of different pore diameters

Weon Sik Chae, Yong Rok Kim, Jin Seung Jung

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Structural confinement effects of amorphous ternary chalcogenide of Ni3(SbTe3)2 in mesoporous channels of different pore diameters have been studied. Insertion of the guest into the channels of AlMCM-41 was probed by the results of transmission electron microscopy (TEM), nitrogen adsorption, X-ray diffraction (XRD), and photoluminescence (PL) and photoluminescence excitation (PLE). From powder XRD patterns, characteristic diffraction peaks were observed for the ternary chalcogenide incorporated in AlMCM-41, which indicated long-range ordering and increased crystallinity. The competition between the homogeneous broadening and the inhomogeneous broadening of the characteristic XRD peak profiles of the guest chalcogenides are evaluated in a series of the hosts. As the mesopore diameter decreases, the strain is enlarged in the nanosize guest chalcogenide while the estimated particle size from the full width at half-maximum (fwhm) of the respective Lorentzian profiles is similarly preserved. The characteristic energy level, for the nanophase ternary chalcogenide, induced by the strain is gradually red shifted in the nanocomposites with decreasing the pore diameter. The structural confinement causes the suppression of phonon coupling to the photoexcited carriers in the ternary chalcogenide incorporated in AlMCM-41, and the coupling is more suppressed in the nanocomposite of smaller pore diameter. Such phonon suppression induced by the structural confinement results in longer PL lifetimes as the pore diameter decreases.

Original languageEnglish
Pages (from-to)1585-1591
Number of pages7
JournalJournal of Physical Chemistry B
Volume107
Issue number7
DOIs
Publication statusPublished - 2003 Feb 20

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Photoluminescence
porosity
Nanocomposites
X ray diffraction
Chalcogenides
photoluminescence
Full width at half maximum
nanocomposites
Electron energy levels
Diffraction patterns
diffraction
retarding
Nitrogen
Diffraction
Particle size
x rays
chalcogenides
Transmission electron microscopy
Adsorption
Powders

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

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title = "Structural confinement effects of ternary chalcogenide in mesoporous ALMCM-41 of different pore diameters",
abstract = "Structural confinement effects of amorphous ternary chalcogenide of Ni3(SbTe3)2 in mesoporous channels of different pore diameters have been studied. Insertion of the guest into the channels of AlMCM-41 was probed by the results of transmission electron microscopy (TEM), nitrogen adsorption, X-ray diffraction (XRD), and photoluminescence (PL) and photoluminescence excitation (PLE). From powder XRD patterns, characteristic diffraction peaks were observed for the ternary chalcogenide incorporated in AlMCM-41, which indicated long-range ordering and increased crystallinity. The competition between the homogeneous broadening and the inhomogeneous broadening of the characteristic XRD peak profiles of the guest chalcogenides are evaluated in a series of the hosts. As the mesopore diameter decreases, the strain is enlarged in the nanosize guest chalcogenide while the estimated particle size from the full width at half-maximum (fwhm) of the respective Lorentzian profiles is similarly preserved. The characteristic energy level, for the nanophase ternary chalcogenide, induced by the strain is gradually red shifted in the nanocomposites with decreasing the pore diameter. The structural confinement causes the suppression of phonon coupling to the photoexcited carriers in the ternary chalcogenide incorporated in AlMCM-41, and the coupling is more suppressed in the nanocomposite of smaller pore diameter. Such phonon suppression induced by the structural confinement results in longer PL lifetimes as the pore diameter decreases.",
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Structural confinement effects of ternary chalcogenide in mesoporous ALMCM-41 of different pore diameters. / Chae, Weon Sik; Kim, Yong Rok; Jung, Jin Seung.

In: Journal of Physical Chemistry B, Vol. 107, No. 7, 20.02.2003, p. 1585-1591.

Research output: Contribution to journalArticle

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