Structural control of hierarchically-ordered TiO2 films by water for dye-sensitized solar cells

Sung Hoon Ahn, Dong Jun Kim, Dong Kyu Roh, Won Seok Chi, Jong Hak Kim

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A facile way of controlling the structure of TiO2 by changing the amount of water to improve the efficiency of dye-sensitized solar cells (DSSCs) is reported. Hierarchically ordered TiO2 films with high porosity and good interconnectivity are synthesized in a well-defined morphological confinement arising from a one-step self-assembly of preformed TiO2 (pre-TiO2) nanocrystals and a graft copolymer, namely poly(vinyl chloride)-g-poly(oxyethylene methacrylate). The polymer-solvent interactions in solution, which are tuned by the amount of water, are shown to be a decisive factor in determining TiO2 morphology and device performance. Systematic control of wall and pore size is achieved and enables the bifunctionality of excellent light scattering properties and easy electron transport through the film. These properties are characterized by reflectance spectroscopy, incident photon-to-electron conversion efficiency, and electrochemical impedance spectroscopy analyses. The TiO2 photoanode that is prepared with a higher water ratio, [pre-TiO2]:[H 2O]=1:0.3, shows a larger surface area, greater light scattering, and better electron transport, which result in a high efficiency (7.7-%) DSSC with a solid polymerized ionic liquid. This efficiency is much greater than that of commercially available TiO2 paste (4.0-%). Dye-sensitized solar cells: Crack-free, hierarchically-ordered TiO2 films with bimodal pores, high porosity, good interconnectivity, and excellent light scattering properties result in high efficiency dye-sensitized solar cells if combined with solid polymerized ionic liquids (7.7-% at 100 mW-cm-2).

Original languageEnglish
Pages (from-to)1841-1848
Number of pages8
JournalChemPhysChem
Volume15
Issue number9
DOIs
Publication statusPublished - 2014 Jun 23

Fingerprint

solar cells
dyes
Light scattering
Ionic Liquids
Water
porosity
light scattering
water
Porosity
Graft copolymers
Ointments
Electrochemical impedance spectroscopy
electrons
Nanocrystals
Self assembly
Conversion efficiency
Pore size
liquids
Polymers
Photons

All Science Journal Classification (ASJC) codes

  • Atomic and Molecular Physics, and Optics
  • Physical and Theoretical Chemistry

Cite this

Ahn, Sung Hoon ; Kim, Dong Jun ; Roh, Dong Kyu ; Chi, Won Seok ; Kim, Jong Hak. / Structural control of hierarchically-ordered TiO2 films by water for dye-sensitized solar cells. In: ChemPhysChem. 2014 ; Vol. 15, No. 9. pp. 1841-1848.
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Structural control of hierarchically-ordered TiO2 films by water for dye-sensitized solar cells. / Ahn, Sung Hoon; Kim, Dong Jun; Roh, Dong Kyu; Chi, Won Seok; Kim, Jong Hak.

In: ChemPhysChem, Vol. 15, No. 9, 23.06.2014, p. 1841-1848.

Research output: Contribution to journalArticle

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T1 - Structural control of hierarchically-ordered TiO2 films by water for dye-sensitized solar cells

AU - Ahn, Sung Hoon

AU - Kim, Dong Jun

AU - Roh, Dong Kyu

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AU - Kim, Jong Hak

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N2 - A facile way of controlling the structure of TiO2 by changing the amount of water to improve the efficiency of dye-sensitized solar cells (DSSCs) is reported. Hierarchically ordered TiO2 films with high porosity and good interconnectivity are synthesized in a well-defined morphological confinement arising from a one-step self-assembly of preformed TiO2 (pre-TiO2) nanocrystals and a graft copolymer, namely poly(vinyl chloride)-g-poly(oxyethylene methacrylate). The polymer-solvent interactions in solution, which are tuned by the amount of water, are shown to be a decisive factor in determining TiO2 morphology and device performance. Systematic control of wall and pore size is achieved and enables the bifunctionality of excellent light scattering properties and easy electron transport through the film. These properties are characterized by reflectance spectroscopy, incident photon-to-electron conversion efficiency, and electrochemical impedance spectroscopy analyses. The TiO2 photoanode that is prepared with a higher water ratio, [pre-TiO2]:[H 2O]=1:0.3, shows a larger surface area, greater light scattering, and better electron transport, which result in a high efficiency (7.7-%) DSSC with a solid polymerized ionic liquid. This efficiency is much greater than that of commercially available TiO2 paste (4.0-%). Dye-sensitized solar cells: Crack-free, hierarchically-ordered TiO2 films with bimodal pores, high porosity, good interconnectivity, and excellent light scattering properties result in high efficiency dye-sensitized solar cells if combined with solid polymerized ionic liquids (7.7-% at 100 mW-cm-2).

AB - A facile way of controlling the structure of TiO2 by changing the amount of water to improve the efficiency of dye-sensitized solar cells (DSSCs) is reported. Hierarchically ordered TiO2 films with high porosity and good interconnectivity are synthesized in a well-defined morphological confinement arising from a one-step self-assembly of preformed TiO2 (pre-TiO2) nanocrystals and a graft copolymer, namely poly(vinyl chloride)-g-poly(oxyethylene methacrylate). The polymer-solvent interactions in solution, which are tuned by the amount of water, are shown to be a decisive factor in determining TiO2 morphology and device performance. Systematic control of wall and pore size is achieved and enables the bifunctionality of excellent light scattering properties and easy electron transport through the film. These properties are characterized by reflectance spectroscopy, incident photon-to-electron conversion efficiency, and electrochemical impedance spectroscopy analyses. The TiO2 photoanode that is prepared with a higher water ratio, [pre-TiO2]:[H 2O]=1:0.3, shows a larger surface area, greater light scattering, and better electron transport, which result in a high efficiency (7.7-%) DSSC with a solid polymerized ionic liquid. This efficiency is much greater than that of commercially available TiO2 paste (4.0-%). Dye-sensitized solar cells: Crack-free, hierarchically-ordered TiO2 films with bimodal pores, high porosity, good interconnectivity, and excellent light scattering properties result in high efficiency dye-sensitized solar cells if combined with solid polymerized ionic liquids (7.7-% at 100 mW-cm-2).

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