Abstract
The stability order of various alkyl, allyl, and benzyl carbocations was investigated using the novel technique for comparing the stability of carbocations in solution developed by using a simple CSI reaction with various ethers. The p-methoxycinnamyl carbocation was the most stable in our reaction system and the next stable carbocation was the p-methoxybenzyl carbocation. The stability of the other carbocations decreased with methacryl, t-butyl, cinnamyl, acryl, benzyl, 2° and allyl carbocations in that order.
| Original language | English |
|---|---|
| Pages (from-to) | 4395-4402 |
| Number of pages | 8 |
| Journal | Tetrahedron |
| Volume | 58 |
| Issue number | 22 |
| DOIs | |
| Publication status | Published - 2002 May 27 |
All Science Journal Classification (ASJC) codes
- Biochemistry
- Drug Discovery
- Organic Chemistry
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Kim, J. D., Han, G., Jeong, L. S., Park, H. J., Zee, O. P., & Jung, Y. H. (2002). Study of the stability of carbocations by chlorosulfonyl isocyanate reaction with ethers. Tetrahedron, 58(22), 4395-4402. https://doi.org/10.1016/S0040-4020(02)00413-1