Superior dehydration of CH3OH over double layer bed of solid acid catalysts - A novel approach for dimethyl ether (DME) synthesis

Hyun Seog Roh; Ki Won Jun; Jae Woo Kim; Venkataraman Vishwanathan

doi:10.1246/cl.2004.598

Superior dehydration of CH₃OH over double layer bed of solid acid catalysts - A novel approach for dimethyl ether (DME) synthesis

Hyun Seog Roh, Ki Won Jun, Jae Woo Kim, Venkataraman Vishwanathan

Division of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

A novel catalyst bed packed with two layers of γ-Al₂O ₃ and Na-H-ZSM-5 showed an outstanding CH₃OH dehydration activity, total selectivity to DME and longer stability during the reaction time. The TPD of NH₃ confirmed that appropriate amounts of Na-impregnation on H-ZSM-5 drastically reduced the strong acid-sites resulting in 100% selectivity to DME.

Original language	English
Pages (from-to)	598-599
Number of pages	2
Journal	Chemistry Letters
Volume	33
Issue number	5
DOIs	https://doi.org/10.1246/cl.2004.598
Publication status	Published - 2004 May 5

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2004.598

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abstract = "A novel catalyst bed packed with two layers of γ-Al2O 3 and Na-H-ZSM-5 showed an outstanding CH3OH dehydration activity, total selectivity to DME and longer stability during the reaction time. The TPD of NH3 confirmed that appropriate amounts of Na-impregnation on H-ZSM-5 drastically reduced the strong acid-sites resulting in 100% selectivity to DME.",

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AU - Vishwanathan, Venkataraman

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AB - A novel catalyst bed packed with two layers of γ-Al2O 3 and Na-H-ZSM-5 showed an outstanding CH3OH dehydration activity, total selectivity to DME and longer stability during the reaction time. The TPD of NH3 confirmed that appropriate amounts of Na-impregnation on H-ZSM-5 drastically reduced the strong acid-sites resulting in 100% selectivity to DME.

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Superior dehydration of CH₃OH over double layer bed of solid acid catalysts - A novel approach for dimethyl ether (DME) synthesis

Abstract

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