Suppressing buoyant force: New avenue for long-term durability of oxygen evolution catalysts

Sungsoon Kim; Changui Ahn; Yoonjun Cho; Gayea Hyun; Seokwoo Jeon; Jong Hyeok Park

doi:10.1016/j.nanoen.2018.10.009

Suppressing buoyant force: New avenue for long-term durability of oxygen evolution catalysts

Sungsoon Kim, Changui Ahn, Yoonjun Cho, Gayea Hyun, Seokwoo Jeon, Jong Hyeok Park

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Recent progress in the development of water oxidation electrocatalysts has mainly focused on achieving high performance in a single measurement, while the importance of durability has not yet been deeply studied. Additionally, oxygen evolution reaction (OER) involves a phase transition from a liquid to a gas, and thus, the removal of the generated oxygen bubble is an important factor for improving the activity or maintaining the performance. In this study, 3D ordered nanoporous nickel electrode is synthesized with a thickness of 5 µm by using a templating method composed of proximity field nanopatterning (PnP) and electrodeposition followed by introduction of NiFe(OH)₂ on the nickel electrode to increase the OER activity. The unique nanopore array structure of the electrode has advantages of not only an enlarged active surface area but also the fast removal of oxygen bubbles by spatial confinement effect. Consequently, the NiFe-decorated 3D ordered nanoporous nickel electrode shows a highly efficient oxygen-evolving ability with a turnover frequency of 2.9 s⁻¹ and an ultralong durability of 300 h.

Original language	English
Pages (from-to)	184-191
Number of pages	8
Journal	Nano Energy
Volume	54
DOIs	https://doi.org/10.1016/j.nanoen.2018.10.009
Publication status	Published - 2018 Dec

Bibliographical note

Funding Information:
This work is mainly supported by the NRF of Korea Grant funded by the Ministry of Science, ICT, and Future Planning ( NRF-2016R1A2A1A05005216, 2015M1A2A2074663, 2016M3D3A1A01913254 ). S. Jeon acknowledges the support by the Multi-Ministry Collaborative R&D Program (Development of Techniques for Identification and Analysis of Gas Molecules to Protect Against Toxic Substances) through the National Research Foundation of Korea (NRF) funded by KNPA, MSIT, MOTIE, ME, and NFA ( 2017M3D9A1073501 ).

Publisher Copyright:
© 2018

All Science Journal Classification (ASJC) codes

Renewable Energy, Sustainability and the Environment
Materials Science(all)
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following Sustainable Development Goal(s)

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title = "Suppressing buoyant force: New avenue for long-term durability of oxygen evolution catalysts",

abstract = "Recent progress in the development of water oxidation electrocatalysts has mainly focused on achieving high performance in a single measurement, while the importance of durability has not yet been deeply studied. Additionally, oxygen evolution reaction (OER) involves a phase transition from a liquid to a gas, and thus, the removal of the generated oxygen bubble is an important factor for improving the activity or maintaining the performance. In this study, 3D ordered nanoporous nickel electrode is synthesized with a thickness of 5 µm by using a templating method composed of proximity field nanopatterning (PnP) and electrodeposition followed by introduction of NiFe(OH)2 on the nickel electrode to increase the OER activity. The unique nanopore array structure of the electrode has advantages of not only an enlarged active surface area but also the fast removal of oxygen bubbles by spatial confinement effect. Consequently, the NiFe-decorated 3D ordered nanoporous nickel electrode shows a highly efficient oxygen-evolving ability with a turnover frequency of 2.9 s−1 and an ultralong durability of 300 h.",

author = "Sungsoon Kim and Changui Ahn and Yoonjun Cho and Gayea Hyun and Seokwoo Jeon and Park, {Jong Hyeok}",

note = "Funding Information: This work is mainly supported by the NRF of Korea Grant funded by the Ministry of Science, ICT, and Future Planning ( NRF-2016R1A2A1A05005216, 2015M1A2A2074663, 2016M3D3A1A01913254 ). S. Jeon acknowledges the support by the Multi-Ministry Collaborative R&D Program (Development of Techniques for Identification and Analysis of Gas Molecules to Protect Against Toxic Substances) through the National Research Foundation of Korea (NRF) funded by KNPA, MSIT, MOTIE, ME, and NFA ( 2017M3D9A1073501 ). Publisher Copyright: {\textcopyright} 2018",

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AU - Jeon, Seokwoo

AU - Park, Jong Hyeok

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N2 - Recent progress in the development of water oxidation electrocatalysts has mainly focused on achieving high performance in a single measurement, while the importance of durability has not yet been deeply studied. Additionally, oxygen evolution reaction (OER) involves a phase transition from a liquid to a gas, and thus, the removal of the generated oxygen bubble is an important factor for improving the activity or maintaining the performance. In this study, 3D ordered nanoporous nickel electrode is synthesized with a thickness of 5 µm by using a templating method composed of proximity field nanopatterning (PnP) and electrodeposition followed by introduction of NiFe(OH)2 on the nickel electrode to increase the OER activity. The unique nanopore array structure of the electrode has advantages of not only an enlarged active surface area but also the fast removal of oxygen bubbles by spatial confinement effect. Consequently, the NiFe-decorated 3D ordered nanoporous nickel electrode shows a highly efficient oxygen-evolving ability with a turnover frequency of 2.9 s−1 and an ultralong durability of 300 h.

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Suppressing buoyant force: New avenue for long-term durability of oxygen evolution catalysts

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

UN SDGs

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