Abstract
A novel strategy for constructing a vertical arrangement of bicontinuous donor-acceptor arrays on a semiconducting electrode has been developed. The relationship between the film structure and the photoelectrochemical properties has been elucidated as a function of the number of donor layers for the first time. The maximum incident photon-to-current efficiency value (21%) is comparable to the highest value (20%) reported for vertical arrangements of bicontinuous donor-acceptor arrays on electrodes.
| Original language | English |
|---|---|
| Pages (from-to) | 3198-3200 |
| Number of pages | 3 |
| Journal | Journal of the American Chemical Society |
| Volume | 131 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - 2009 Mar 11 |
All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
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Kira, A., Umeyama, T., Matano, Y., Yoshida, K., Isoda, S., Park, J. K., Kim, D., & Imahori, H. (2009). Supramolecular donor-acceptor heterojunctions by vectorial stepwise assembly of porphyrins and coordination-bonded fullerene arrays for photocurrent generation. Journal of the American Chemical Society, 131(9), 3198-3200. https://doi.org/10.1021/ja8096465